Reaction of [FeCo(CO)7(μ-CH=CRH)] (R = H or Ph) with dimethylphenylphosphine. Synthesis and structure of [FeCo(CO)4(μ-CO)-(PMe2Ph)2(μ-CH=CH2)], an electronically unbalanced iron-cobalt complex

Isabel Moldes, Josep Ros, Ramón Yañez, René Mathieu, Xavier Solans, Mercé Font-Bardí

Research output: Contribution to journalArticleResearchpeer-review

10 Citations (Scopus)

Abstract

The reaction of [FeCo(CO)7(μ-CH=CRH)] (R = H or Ph) with PMe2Ph leads to complexes [FeCo(CO)6(PMe2Ph)(μ-CH=CPhH)] and [FeCo(CO)5(PMe2Ph)2(μ-CH=CRH)]. The disubstituted compounds contain two PMe2Ph ligands linked to iron and two bridging ligands, carbonyl and vinyl. The structure of [FeCo(CO)4(μ-CO)(PMe2Ph)2(μ-CH=CH 2)] has been solved by X-ray diffraction methods.
Original languageEnglish
Pages (from-to)1417-1419
JournalJournal of the Chemical Society, Dalton Transactions
Issue number5
DOIs
Publication statusPublished - 1 Dec 1988

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