Reaction of [FeCo(CO)7(μ-CH=CRH)] (R = H or Ph) with dimethylphenylphosphine. Synthesis and structure of [FeCo(CO)4(μ-CO)-(PMe2Ph)2(μ-CH=CH2)], an electronically unbalanced iron-cobalt complex

Isabel Moldes; Josep Ros; Ramón Yañez; René Mathieu; Xavier Solans; Mercé Font-Bardí

doi:10.1039/DT9880001417

Reaction of [FeCo(CO)₇(μ-CH=CRH)] (R = H or Ph) with dimethylphenylphosphine. Synthesis and structure of [FeCo(CO)₄(μ-CO)-(PMe₂Ph)₂(μ-CH=CH₂)], an electronically unbalanced iron-cobalt complex

Isabel Moldes, Josep Ros, Ramón Yañez, René Mathieu, Xavier Solans, Mercé Font-Bardí

Department of Chemistry

Research output: Contribution to journal › Article › Research › peer-review

11 Citations (Scopus)

Abstract

The reaction of [FeCo(CO)7(μ-CH=CRH)] (R = H or Ph) with PMe2Ph leads to complexes [FeCo(CO)6(PMe2Ph)(μ-CH=CPhH)] and [FeCo(CO)5(PMe2Ph)2(μ-CH=CRH)]. The disubstituted compounds contain two PMe2Ph ligands linked to iron and two bridging ligands, carbonyl and vinyl. The structure of [FeCo(CO)4(μ-CO)(PMe2Ph)2(μ-CH=CH 2)] has been solved by X-ray diffraction methods.

Original language	English
Pages (from-to)	1417-1419
Journal	Journal of the Chemical Society, Dalton Transactions
Issue number	5
DOIs	https://doi.org/10.1039/DT9880001417
Publication status	Published - 1 Dec 1988

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10.1039/DT9880001417

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Moldes, I., Ros, J., Yañez, R., Mathieu, R., Solans, X., & Font-Bardí, M. (1988). Reaction of [FeCo(CO)₇(μ-CH=CRH)] (R = H or Ph) with dimethylphenylphosphine. Synthesis and structure of [FeCo(CO)₄(μ-CO)-(PMe₂Ph)₂(μ-CH=CH₂)], an electronically unbalanced iron-cobalt complex. Journal of the Chemical Society, Dalton Transactions, (5), 1417-1419. https://doi.org/10.1039/DT9880001417

@article{36a5ad4d1a3243b3a1e655ac7493f31b,

title = "Reaction of [FeCo(CO)7(μ-CH=CRH)] (R = H or Ph) with dimethylphenylphosphine. Synthesis and structure of [FeCo(CO)4(μ-CO)-(PMe2Ph)2(μ-CH=CH2)], an electronically unbalanced iron-cobalt complex",

abstract = "The reaction of [FeCo(CO)7(μ-CH=CRH)] (R = H or Ph) with PMe2Ph leads to complexes [FeCo(CO)6(PMe2Ph)(μ-CH=CPhH)] and [FeCo(CO)5(PMe2Ph)2(μ-CH=CRH)]. The disubstituted compounds contain two PMe2Ph ligands linked to iron and two bridging ligands, carbonyl and vinyl. The structure of [FeCo(CO)4(μ-CO)(PMe2Ph)2(μ-CH=CH 2)] has been solved by X-ray diffraction methods.",

author = "Isabel Moldes and Josep Ros and Ram{\'o}n Ya{\~n}ez and Ren{\'e} Mathieu and Xavier Solans and Merc{\'e} Font-Bard{\'i}",

year = "1988",

month = dec,

day = "1",

doi = "10.1039/DT9880001417",

language = "English",

pages = "1417--1419",

number = "5",

}

Moldes, I, Ros, J, Yañez, R, Mathieu, R, Solans, X & Font-Bardí, M 1988, 'Reaction of [FeCo(CO)₇(μ-CH=CRH)] (R = H or Ph) with dimethylphenylphosphine. Synthesis and structure of [FeCo(CO)₄(μ-CO)-(PMe₂Ph)₂(μ-CH=CH₂)], an electronically unbalanced iron-cobalt complex', Journal of the Chemical Society, Dalton Transactions, no. 5, pp. 1417-1419. https://doi.org/10.1039/DT9880001417

Reaction of [FeCo(CO)₇(μ-CH=CRH)] (R = H or Ph) with dimethylphenylphosphine. Synthesis and structure of [FeCo(CO)₄(μ-CO)-(PMe₂Ph)₂(μ-CH=CH₂)], an electronically unbalanced iron-cobalt complex. / Moldes, Isabel; Ros, Josep; Yañez, Ramón et al.

In: Journal of the Chemical Society, Dalton Transactions, No. 5, 01.12.1988, p. 1417-1419.

Research output: Contribution to journal › Article › Research › peer-review

TY - JOUR

T1 - Reaction of [FeCo(CO)7(μ-CH=CRH)] (R = H or Ph) with dimethylphenylphosphine. Synthesis and structure of [FeCo(CO)4(μ-CO)-(PMe2Ph)2(μ-CH=CH2)], an electronically unbalanced iron-cobalt complex

AU - Moldes, Isabel

AU - Ros, Josep

AU - Yañez, Ramón

AU - Mathieu, René

AU - Solans, Xavier

AU - Font-Bardí, Mercé

PY - 1988/12/1

Y1 - 1988/12/1

N2 - The reaction of [FeCo(CO)7(μ-CH=CRH)] (R = H or Ph) with PMe2Ph leads to complexes [FeCo(CO)6(PMe2Ph)(μ-CH=CPhH)] and [FeCo(CO)5(PMe2Ph)2(μ-CH=CRH)]. The disubstituted compounds contain two PMe2Ph ligands linked to iron and two bridging ligands, carbonyl and vinyl. The structure of [FeCo(CO)4(μ-CO)(PMe2Ph)2(μ-CH=CH 2)] has been solved by X-ray diffraction methods.

AB - The reaction of [FeCo(CO)7(μ-CH=CRH)] (R = H or Ph) with PMe2Ph leads to complexes [FeCo(CO)6(PMe2Ph)(μ-CH=CPhH)] and [FeCo(CO)5(PMe2Ph)2(μ-CH=CRH)]. The disubstituted compounds contain two PMe2Ph ligands linked to iron and two bridging ligands, carbonyl and vinyl. The structure of [FeCo(CO)4(μ-CO)(PMe2Ph)2(μ-CH=CH 2)] has been solved by X-ray diffraction methods.

U2 - 10.1039/DT9880001417

DO - 10.1039/DT9880001417

M3 - Article

SP - 1417

EP - 1419

IS - 5

ER -

Reaction of [FeCo(CO)7(μ-CH=CRH)] (R = H or Ph) with dimethylphenylphosphine. Synthesis and structure of [FeCo(CO)4(μ-CO)-(PMe2Ph)2(μ-CH=CH2)], an electronically unbalanced iron-cobalt complex

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Reaction of [FeCo(CO)₇(μ-CH=CRH)] (R = H or Ph) with dimethylphenylphosphine. Synthesis and structure of [FeCo(CO)₄(μ-CO)-(PMe₂Ph)₂(μ-CH=CH₂)], an electronically unbalanced iron-cobalt complex