Rationale for the sluggish oxidative addition of aryl halides to Au(I)

Madeleine Livendahl; Charles Goehry; Feliu Maseras; Antonio M. Echavarren

doi:10.1039/c3cc48914k

Rationale for the sluggish oxidative addition of aryl halides to Au(I)

Madeleine Livendahl, Charles Goehry, Feliu Maseras, Antonio M. Echavarren

Department of Chemistry

Research output: Contribution to journal › Article › Research › peer-review

53 Citations (Scopus)

Abstract

The oxidative addition of C<inf>sp</inf><sup>2</sup>-Br or C <inf>sp</inf><sup>2</sup>-I bonds to gold(i) does not take place even under very favorable intramolecular conditions that could form five- or six-membered gold(iii) metallacycles. DFT calculations reveal that although this process could be feasible thermodynamically, it is kinetically very sluggish. © The Royal Society of Chemistry.

Original language	English
Pages (from-to)	1533-1536
Journal	Chemical Communications
Volume	50
Issue number	13
DOIs	https://doi.org/10.1039/c3cc48914k
Publication status	Published - 14 Feb 2014

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title = "Rationale for the sluggish oxidative addition of aryl halides to Au(I)",

abstract = "The oxidative addition of Csp2-Br or C sp2-I bonds to gold(i) does not take place even under very favorable intramolecular conditions that could form five- or six-membered gold(iii) metallacycles. DFT calculations reveal that although this process could be feasible thermodynamically, it is kinetically very sluggish. {\textcopyright} The Royal Society of Chemistry.",

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PY - 2014/2/14

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N2 - The oxidative addition of Csp2-Br or C sp2-I bonds to gold(i) does not take place even under very favorable intramolecular conditions that could form five- or six-membered gold(iii) metallacycles. DFT calculations reveal that although this process could be feasible thermodynamically, it is kinetically very sluggish. © The Royal Society of Chemistry.

AB - The oxidative addition of Csp2-Br or C sp2-I bonds to gold(i) does not take place even under very favorable intramolecular conditions that could form five- or six-membered gold(iii) metallacycles. DFT calculations reveal that although this process could be feasible thermodynamically, it is kinetically very sluggish. © The Royal Society of Chemistry.

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DO - 10.1039/c3cc48914k

M3 - Article

VL - 50

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EP - 1536

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Rationale for the sluggish oxidative addition of aryl halides to Au(I)

Abstract

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