Proton abstraction mechanism for the palladium-catalyzed intramolecular arylation

Domingo García-Cuadrado; Ataualpa A C Braga; Feliu Maseras; Antonio M. Echavarren

doi:10.1021/ja056165v

Proton abstraction mechanism for the palladium-catalyzed intramolecular arylation

Domingo García-Cuadrado, Ataualpa A C Braga, Feliu Maseras, Antonio M. Echavarren

Department of Chemistry

Research output: Contribution to journal › Article › Research › peer-review

575 Citations (Scopus)

Abstract

Under the usual conditions, the Pd-catalyzed arylation does not involve an electrophilic aromatic substitution reaction. On the basis of DFT calculations, we propose a mechanism for the Pd-catalyzed arylation that involves a proton abstraction by a carbonate or related ligand and that provides a satisfactory explanation for the experimental data. Copyright © 2006 American Chemical Society.

Original language	English
Pages (from-to)	1066-1067
Journal	Journal of the American Chemical Society
Volume	128
Issue number	4
DOIs	https://doi.org/10.1021/ja056165v
Publication status	Published - 1 Feb 2006

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García-Cuadrado, D., Braga, A. A. C., Maseras, F., & Echavarren, A. M. (2006). Proton abstraction mechanism for the palladium-catalyzed intramolecular arylation. Journal of the American Chemical Society, 128(4), 1066-1067. https://doi.org/10.1021/ja056165v

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abstract = "Under the usual conditions, the Pd-catalyzed arylation does not involve an electrophilic aromatic substitution reaction. On the basis of DFT calculations, we propose a mechanism for the Pd-catalyzed arylation that involves a proton abstraction by a carbonate or related ligand and that provides a satisfactory explanation for the experimental data. Copyright {\textcopyright} 2006 American Chemical Society.",

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AU - Maseras, Feliu

AU - Echavarren, Antonio M.

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AB - Under the usual conditions, the Pd-catalyzed arylation does not involve an electrophilic aromatic substitution reaction. On the basis of DFT calculations, we propose a mechanism for the Pd-catalyzed arylation that involves a proton abstraction by a carbonate or related ligand and that provides a satisfactory explanation for the experimental data. Copyright © 2006 American Chemical Society.

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