Proton abstraction mechanism for the palladium-catalyzed intramolecular arylation

Domingo García-Cuadrado, Ataualpa A C Braga, Feliu Maseras, Antonio M. Echavarren

Research output: Contribution to journalArticleResearchpeer-review

575 Citations (Scopus)

Abstract

Under the usual conditions, the Pd-catalyzed arylation does not involve an electrophilic aromatic substitution reaction. On the basis of DFT calculations, we propose a mechanism for the Pd-catalyzed arylation that involves a proton abstraction by a carbonate or related ligand and that provides a satisfactory explanation for the experimental data. Copyright © 2006 American Chemical Society.
Original languageEnglish
Pages (from-to)1066-1067
JournalJournal of the American Chemical Society
Volume128
Issue number4
DOIs
Publication statusPublished - 1 Feb 2006

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