Proton abstraction mechanism for the palladium-catalyzed intramolecular arylation

Domingo García-Cuadrado; Ataualpa A C Braga; Feliu Maseras; Antonio M. Echavarren

doi:10.1021/ja056165v

Proton abstraction mechanism for the palladium-catalyzed intramolecular arylation

Domingo García-Cuadrado, Ataualpa A C Braga, Feliu Maseras, Antonio M. Echavarren

Department of Chemistry

Research output: Contribution to journal › Article › Research › peer-review

621 Citations (Scopus)

Abstract

Under the usual conditions, the Pd-catalyzed arylation does not involve an electrophilic aromatic substitution reaction. On the basis of DFT calculations, we propose a mechanism for the Pd-catalyzed arylation that involves a proton abstraction by a carbonate or related ligand and that provides a satisfactory explanation for the experimental data. Copyright © 2006 American Chemical Society.

Original language	English
Pages (from-to)	1066-1067
Journal	Journal of the American Chemical Society
Volume	128
Issue number	4
DOIs	https://doi.org/10.1021/ja056165v
Publication status	Published - 1 Feb 2006

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title = "Proton abstraction mechanism for the palladium-catalyzed intramolecular arylation",

abstract = "Under the usual conditions, the Pd-catalyzed arylation does not involve an electrophilic aromatic substitution reaction. On the basis of DFT calculations, we propose a mechanism for the Pd-catalyzed arylation that involves a proton abstraction by a carbonate or related ligand and that provides a satisfactory explanation for the experimental data. Copyright {\textcopyright} 2006 American Chemical Society.",

author = "Domingo Garc{\'i}a-Cuadrado and Braga, {Ataualpa A C} and Feliu Maseras and Echavarren, {Antonio M.}",

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T1 - Proton abstraction mechanism for the palladium-catalyzed intramolecular arylation

AU - García-Cuadrado, Domingo

AU - Braga, Ataualpa A C

AU - Maseras, Feliu

AU - Echavarren, Antonio M.

PY - 2006/2/1

Y1 - 2006/2/1

N2 - Under the usual conditions, the Pd-catalyzed arylation does not involve an electrophilic aromatic substitution reaction. On the basis of DFT calculations, we propose a mechanism for the Pd-catalyzed arylation that involves a proton abstraction by a carbonate or related ligand and that provides a satisfactory explanation for the experimental data. Copyright © 2006 American Chemical Society.

AB - Under the usual conditions, the Pd-catalyzed arylation does not involve an electrophilic aromatic substitution reaction. On the basis of DFT calculations, we propose a mechanism for the Pd-catalyzed arylation that involves a proton abstraction by a carbonate or related ligand and that provides a satisfactory explanation for the experimental data. Copyright © 2006 American Chemical Society.

U2 - 10.1021/ja056165v

DO - 10.1021/ja056165v

M3 - Article

VL - 128

SP - 1066

EP - 1067

JO - Journal of the American Chemical Society

JF - Journal of the American Chemical Society

SN - 0002-7863

IS - 4

ER -

Proton abstraction mechanism for the palladium-catalyzed intramolecular arylation

Abstract

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