TY - JOUR
T1 - Protection strategies for directionally-controlled synthesis of previously inaccessible metal-organic polyhedra (MOPs): The cases of carboxylate: The amino-functionalised Rh(ii)-MOPs
AU - Albalad, Jorge
AU - Carné-Sánchez, Arnau
AU - Grancha, Thais
AU - Hernández-López, Laura
AU - Maspoch, Daniel
PY - 2019/1/1
Y1 - 2019/1/1
N2 - This journal is © The Royal Society of Chemistry. Herein we report that strategic use of protecting groups in coordination reactions enables directional inhibition that leads to synthesis of highly functionalised metal-organic polyhedra (MOPs), rather than of the extended coordination networks. Using this approach, we functionalised two new porous cuboctahedral Rh(ii)-based MOPs with 24 peripheral carboxylic acid groups or 24 peripheral amino groups.
AB - This journal is © The Royal Society of Chemistry. Herein we report that strategic use of protecting groups in coordination reactions enables directional inhibition that leads to synthesis of highly functionalised metal-organic polyhedra (MOPs), rather than of the extended coordination networks. Using this approach, we functionalised two new porous cuboctahedral Rh(ii)-based MOPs with 24 peripheral carboxylic acid groups or 24 peripheral amino groups.
U2 - https://doi.org/10.1039/c9cc07083d
DO - https://doi.org/10.1039/c9cc07083d
M3 - Article
C2 - 31591620
VL - 55
SP - 12785
EP - 12788
ER -