Protection strategies for directionally-controlled synthesis of previously inaccessible metal-organic polyhedra (MOPs): The cases of carboxylate: The amino-functionalised Rh(ii)-MOPs

Jorge Albalad, Arnau Carné-Sánchez, Thais Grancha, Laura Hernández-López, Daniel Maspoch

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    12 Citations (Scopus)

    Abstract

    This journal is © The Royal Society of Chemistry. Herein we report that strategic use of protecting groups in coordination reactions enables directional inhibition that leads to synthesis of highly functionalised metal-organic polyhedra (MOPs), rather than of the extended coordination networks. Using this approach, we functionalised two new porous cuboctahedral Rh(ii)-based MOPs with 24 peripheral carboxylic acid groups or 24 peripheral amino groups.
    Original languageEnglish
    Pages (from-to)12785-12788
    JournalChemical Communications
    Volume55
    DOIs
    Publication statusPublished - 1 Jan 2019

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