Production of high purity hydrogen by ethanol steam reforming in membrane reactor

E. Yu Mironova; M. M. Ermilova; N. V. Orekhova; D. N. Muraviev; A. B. Yaroslavtsev

doi:10.1016/j.cattod.2014.01.014

Production of high purity hydrogen by ethanol steam reforming in membrane reactor

E. Yu Mironova, M. M. Ermilova, N. V. Orekhova, D. N. Muraviev, A. B. Yaroslavtsev

Department of Chemistry

Research output: Contribution to journal › Article › Research › peer-review

42 Citations (Scopus)

Abstract

Production of hydrogen in the course of ethanol steam reforming (ESR) on bimetallic Pt-Ni and Pt-Ru nanocatalysts supported on detonation nanodiamonds (DND) was studied in conventional and membrane reactors. The highest hydrogen yield and purity were achieved in the case of Pt-Ru/DND catalysts at total metal content of 0.3% and atomic Pt/Ru ratio of 9/1. It is shown that realization of ESR process in the membrane reactor with simultaneous hydrogen removal through the Pd-Ru membrane produces hydrogen of high purity, free of any other gaseous products. © 2014 Elsevier B.V.

Original language	English
Pages (from-to)	64-69
Journal	Catalysis Today
Volume	236
Issue number	PART A
DOIs	https://doi.org/10.1016/j.cattod.2014.01.014
Publication status	Published - 1 Nov 2014

Keywords

Ethanol steam reforming
Nanodiamond-supported metal catalysts
Pd-Ru membrane reactor

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title = "Production of high purity hydrogen by ethanol steam reforming in membrane reactor",

abstract = "Production of hydrogen in the course of ethanol steam reforming (ESR) on bimetallic Pt-Ni and Pt-Ru nanocatalysts supported on detonation nanodiamonds (DND) was studied in conventional and membrane reactors. The highest hydrogen yield and purity were achieved in the case of Pt-Ru/DND catalysts at total metal content of 0.3% and atomic Pt/Ru ratio of 9/1. It is shown that realization of ESR process in the membrane reactor with simultaneous hydrogen removal through the Pd-Ru membrane produces hydrogen of high purity, free of any other gaseous products. {\textcopyright} 2014 Elsevier B.V.",

keywords = "Ethanol steam reforming, Nanodiamond-supported metal catalysts, Pd-Ru membrane reactor",

author = "Mironova, {E. Yu} and Ermilova, {M. M.} and Orekhova, {N. V.} and Muraviev, {D. N.} and Yaroslavtsev, {A. B.}",

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AU - Mironova, E. Yu

AU - Ermilova, M. M.

AU - Orekhova, N. V.

AU - Muraviev, D. N.

AU - Yaroslavtsev, A. B.

PY - 2014/11/1

Y1 - 2014/11/1

N2 - Production of hydrogen in the course of ethanol steam reforming (ESR) on bimetallic Pt-Ni and Pt-Ru nanocatalysts supported on detonation nanodiamonds (DND) was studied in conventional and membrane reactors. The highest hydrogen yield and purity were achieved in the case of Pt-Ru/DND catalysts at total metal content of 0.3% and atomic Pt/Ru ratio of 9/1. It is shown that realization of ESR process in the membrane reactor with simultaneous hydrogen removal through the Pd-Ru membrane produces hydrogen of high purity, free of any other gaseous products. © 2014 Elsevier B.V.

AB - Production of hydrogen in the course of ethanol steam reforming (ESR) on bimetallic Pt-Ni and Pt-Ru nanocatalysts supported on detonation nanodiamonds (DND) was studied in conventional and membrane reactors. The highest hydrogen yield and purity were achieved in the case of Pt-Ru/DND catalysts at total metal content of 0.3% and atomic Pt/Ru ratio of 9/1. It is shown that realization of ESR process in the membrane reactor with simultaneous hydrogen removal through the Pd-Ru membrane produces hydrogen of high purity, free of any other gaseous products. © 2014 Elsevier B.V.

KW - Ethanol steam reforming

KW - Nanodiamond-supported metal catalysts

KW - Pd-Ru membrane reactor

U2 - 10.1016/j.cattod.2014.01.014

DO - 10.1016/j.cattod.2014.01.014

M3 - Article

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SP - 64

EP - 69

JO - Catalysis Today

JF - Catalysis Today

SN - 0920-5861

IS - PART A

ER -