Preparation, structural and conformational study of cyclobis[(R,R)-α,α′-bis(trifluoromethyl)-9, 10-anthracenedimethylsulphite]

M. Sánchez-Aris, I. Maestre, T. Parella, C. Jaime, A. Virgili, A. Alvarez-Larena, J. F. Piniella

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Abstract

The macrocycle cyclobis[(R,R)-α,α′-bis(trifluoromethyl)-9, 10-anthracenedimethylsulphite) has been prepared and the two possible arrangements have been identified and are described. A conformational study was carried out using NMR and molecular modelling techniques and X-ray diffraction analysis has allowed full assignment of the crystal structure. © 2002 Elsevier Science Ltd. All rights reserved.
Original languageEnglish
Pages (from-to)1231-1236
JournalTetrahedron Asymmetry
Volume13
Issue number12
DOIs
Publication statusPublished - 5 Jul 2002

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