Preparation of transition metal complexes of chiral derivatives of acetoacetic acid. Tetraalkylammonium tetrachlorometallates as an organic source of metals

Nicanor Gálvez; Marcial Moreno-Mañas; Imma Padrós; Rosa Ma Sebastián; Neus Serra; Adelina Vallribera

doi:10.1016/0277-5387(95)00066-2

Preparation of transition metal complexes of chiral derivatives of acetoacetic acid. Tetraalkylammonium tetrachlorometallates as an organic source of metals

Nicanor Gálvez, Marcial Moreno-Mañas, Imma Padrós, Rosa Ma Sebastián, Neus Serra, Adelina Vallribera

Department of Chemistry

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13 Citations (Scopus)

Abstract

Bis(benzyltrimethylammonium) tetrachlorocuprate, tetrachlorocobaltate and hexachlorodiferrate react in organic solvents with alkaline salts of CH3COCH2CO-Xc[Xc-H = (d)-menthol, (4S)-4-benzyl-2-oxazolidinone and (2R)-bornane-10,2-sultam] to give homochiral β-dicarbonyl metal complexes. © 1995.

Original language	English
Pages (from-to)	1397-1399
Journal	Polyhedron
Volume	14
Issue number	10
DOIs	https://doi.org/10.1016/0277-5387(95)00066-2
Publication status	Published - 1 Jan 1995

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title = "Preparation of transition metal complexes of chiral derivatives of acetoacetic acid. Tetraalkylammonium tetrachlorometallates as an organic source of metals",

abstract = "Bis(benzyltrimethylammonium) tetrachlorocuprate, tetrachlorocobaltate and hexachlorodiferrate react in organic solvents with alkaline salts of CH3COCH2CO-Xc[Xc-H = (d)-menthol, (4S)-4-benzyl-2-oxazolidinone and (2R)-bornane-10,2-sultam] to give homochiral β-dicarbonyl metal complexes. {\textcopyright} 1995.",

author = "Nicanor G{\'a}lvez and Marcial Moreno-Ma{\~n}as and Imma Padr{\'o}s and Sebasti{\'a}n, {Rosa Ma} and Neus Serra and Adelina Vallribera",

year = "1995",

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doi = "10.1016/0277-5387(95)00066-2",

language = "English",

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TY - JOUR

T1 - Preparation of transition metal complexes of chiral derivatives of acetoacetic acid. Tetraalkylammonium tetrachlorometallates as an organic source of metals

AU - Gálvez, Nicanor

AU - Moreno-Mañas, Marcial

AU - Padrós, Imma

AU - Sebastián, Rosa Ma

AU - Serra, Neus

AU - Vallribera, Adelina

PY - 1995/1/1

Y1 - 1995/1/1

N2 - Bis(benzyltrimethylammonium) tetrachlorocuprate, tetrachlorocobaltate and hexachlorodiferrate react in organic solvents with alkaline salts of CH3COCH2CO-Xc[Xc-H = (d)-menthol, (4S)-4-benzyl-2-oxazolidinone and (2R)-bornane-10,2-sultam] to give homochiral β-dicarbonyl metal complexes. © 1995.

AB - Bis(benzyltrimethylammonium) tetrachlorocuprate, tetrachlorocobaltate and hexachlorodiferrate react in organic solvents with alkaline salts of CH3COCH2CO-Xc[Xc-H = (d)-menthol, (4S)-4-benzyl-2-oxazolidinone and (2R)-bornane-10,2-sultam] to give homochiral β-dicarbonyl metal complexes. © 1995.

U2 - 10.1016/0277-5387(95)00066-2

DO - 10.1016/0277-5387(95)00066-2

M3 - Article

VL - 14

SP - 1397

EP - 1399

IS - 10

ER -

Preparation of transition metal complexes of chiral derivatives of acetoacetic acid. Tetraalkylammonium tetrachlorometallates as an organic source of metals

Abstract

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