Preparation of (R)- and (S)-1-adamantyl-9-anthrylmethanol. Conformational study and their behaviour as chiral solvating agents

Sandra Almer, Enric Cervelló, Carlos Jaime, Albert Virgili

Research output: Contribution to journalArticleResearchpeer-review

10 Citations (Scopus)

Abstract

Enantiopure forms of 1-adamantyl-9-anthrylmethanol were prepared and a conformational study was carried out by MM and NOE transfer methodologies. The absolute configuration was determined by combining dynamic NMR and theoretical calculations of the carbamate derivatives. The activity as a chiral solvating agent was tested in the presence of oxygenated functional groups.
Original languageEnglish
Pages (from-to)3719-3725
JournalTetrahedron Asymmetry
Volume10
Issue number19
DOIs
Publication statusPublished - 24 Sep 1999

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