Preparation of homochiral 9-anthryl-tert-butylcarbinol. The configurational and conformational NMR study of its carbamate derivatives

Maria de Moragas; Adriana Port; Xavier Sánchez-Ruiz; Carlos Jaime; Christian Roussel; Albert Virgili

doi:10.1016/0957-4166(95)00164-K

Preparation of homochiral 9-anthryl-tert-butylcarbinol. The configurational and conformational NMR study of its carbamate derivatives

Maria de Moragas, Adriana Port, Xavier Sánchez-Ruiz, Carlos Jaime, Christian Roussel, Albert Virgili

Department of Chemistry

Research output: Contribution to journal › Article › Research › peer-review

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Abstract

The homochiral carbamates of 9-anthryl-tert-butylcarbinol were prepared and their conformational equilibrium was studied. The absolute configuration was determined by comparison of the NMR data with MM calculations. The enantiomers of the alcohol were obtained after chromatographic separation of carbamate derivatives and their hydrolysis. The same homochiral alcohols were prepared by direct chiral column chromatography. © 1995.

Original language	English
Pages (from-to)	1307-1310
Journal	Tetrahedron: asymmetry
Volume	6
Issue number	6
DOIs	https://doi.org/10.1016/0957-4166(95)00164-K
Publication status	Published - 1 Jan 1995

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title = "Preparation of homochiral 9-anthryl-tert-butylcarbinol. The configurational and conformational NMR study of its carbamate derivatives",

abstract = "The homochiral carbamates of 9-anthryl-tert-butylcarbinol were prepared and their conformational equilibrium was studied. The absolute configuration was determined by comparison of the NMR data with MM calculations. The enantiomers of the alcohol were obtained after chromatographic separation of carbamate derivatives and their hydrolysis. The same homochiral alcohols were prepared by direct chiral column chromatography. {\textcopyright} 1995.",

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AU - de Moragas, Maria

AU - Port, Adriana

AU - Sánchez-Ruiz, Xavier

AU - Jaime, Carlos

AU - Roussel, Christian

AU - Virgili, Albert

PY - 1995/1/1

Y1 - 1995/1/1

N2 - The homochiral carbamates of 9-anthryl-tert-butylcarbinol were prepared and their conformational equilibrium was studied. The absolute configuration was determined by comparison of the NMR data with MM calculations. The enantiomers of the alcohol were obtained after chromatographic separation of carbamate derivatives and their hydrolysis. The same homochiral alcohols were prepared by direct chiral column chromatography. © 1995.

AB - The homochiral carbamates of 9-anthryl-tert-butylcarbinol were prepared and their conformational equilibrium was studied. The absolute configuration was determined by comparison of the NMR data with MM calculations. The enantiomers of the alcohol were obtained after chromatographic separation of carbamate derivatives and their hydrolysis. The same homochiral alcohols were prepared by direct chiral column chromatography. © 1995.

U2 - 10.1016/0957-4166(95)00164-K

DO - 10.1016/0957-4166(95)00164-K

M3 - Article

VL - 6

SP - 1307

EP - 1310

IS - 6

ER -

Preparation of homochiral 9-anthryl-tert-butylcarbinol. The configurational and conformational NMR study of its carbamate derivatives

Abstract

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