Preparation of enantiomers of 9-(1-amino-2,2-dimethylpropyl)-9,10-dihydroanthracene. Conformational study and their behaviour as chiral solvating agents

Adriana Port; Albert Virgili; Carlos Jaime

doi:10.1016/0957-4166(96)00146-2

Preparation of enantiomers of 9-(1-amino-2,2-dimethylpropyl)-9,10-dihydroanthracene. Conformational study and their behaviour as chiral solvating agents

Adriana Port, Albert Virgili, Carlos Jaime

Department of Chemistry

Research output: Contribution to journal › Article › Research › peer-review

22 Citations (Scopus)

Abstract

Homochiral forms of 9-(1-amino-2,2-dimethylpropyl)-9,10-dihydroanthracene were prepared by hydrolysis of crystallised diastereomeric salts of mandelic acid. The activity as chiral solvating agent was tested in the presence of several alcohols and acids. A boat conformation of the central ring was demonstrated by NMR studies and MM3 calculations.

Original language	English
Pages (from-to)	1295-1302
Journal	Tetrahedron Asymmetry
Volume	7
Issue number	5
DOIs	https://doi.org/10.1016/0957-4166(96)00146-2
Publication status	Published - 1 Jan 1996

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title = "Preparation of enantiomers of 9-(1-amino-2,2-dimethylpropyl)-9,10-dihydroanthracene. Conformational study and their behaviour as chiral solvating agents",

abstract = "Homochiral forms of 9-(1-amino-2,2-dimethylpropyl)-9,10-dihydroanthracene were prepared by hydrolysis of crystallised diastereomeric salts of mandelic acid. The activity as chiral solvating agent was tested in the presence of several alcohols and acids. A boat conformation of the central ring was demonstrated by NMR studies and MM3 calculations.",

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AU - Port, Adriana

AU - Virgili, Albert

AU - Jaime, Carlos

PY - 1996/1/1

Y1 - 1996/1/1

N2 - Homochiral forms of 9-(1-amino-2,2-dimethylpropyl)-9,10-dihydroanthracene were prepared by hydrolysis of crystallised diastereomeric salts of mandelic acid. The activity as chiral solvating agent was tested in the presence of several alcohols and acids. A boat conformation of the central ring was demonstrated by NMR studies and MM3 calculations.

AB - Homochiral forms of 9-(1-amino-2,2-dimethylpropyl)-9,10-dihydroanthracene were prepared by hydrolysis of crystallised diastereomeric salts of mandelic acid. The activity as chiral solvating agent was tested in the presence of several alcohols and acids. A boat conformation of the central ring was demonstrated by NMR studies and MM3 calculations.

U2 - 10.1016/0957-4166(96)00146-2

DO - 10.1016/0957-4166(96)00146-2

M3 - Article

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