Abstract
Homochiral forms of 9-(1-amino-2,2-dimethylpropyl)-9,10-dihydroanthracene were prepared by hydrolysis of crystallised diastereomeric salts of mandelic acid. The activity as chiral solvating agent was tested in the presence of several alcohols and acids. A boat conformation of the central ring was demonstrated by NMR studies and MM3 calculations.
Original language | English |
---|---|
Pages (from-to) | 1295-1302 |
Journal | Tetrahedron Asymmetry |
Volume | 7 |
Issue number | 5 |
DOIs | |
Publication status | Published - 1 Jan 1996 |