Preparation of enantiomers of 1-(1-naphthyl)-2,2-dimethylpropylamine and their behaviour as chiral solvating agents: Study of diastereochemic association by Job's plots and intermolecular NOE measurements

A. Port; A. Virgili; A. Alvarez Alvarez-Larena; J. F. Piniella

doi:10.1016/S0957-4166(00)00334-7

Preparation of enantiomers of 1-(1-naphthyl)-2,2-dimethylpropylamine and their behaviour as chiral solvating agents: Study of diastereochemic association by Job's plots and intermolecular NOE measurements

A. Port, A. Virgili, A. Alvarez Alvarez-Larena, J. F. Piniella

Research output: Contribution to journal › Article › Research › peer-review

31 Citations (Scopus)

Abstract

Enantiomers of 1-(1-naphthyl)-2,2-dimethylpropylamine have been obtained and considered as chiral solvating agents against several compounds. The formed complexes have been studied with the aid of the nuclear Overhauser effect and its stoichiometry by the method of continuous variations. Two diastereoisomeric complexes present similar geometry of association by π-π-stacking of the aromatic rings and by hydrogen bonding of the functional groups. © 2000 Elsevier Science Ltd.

Original language	English
Pages (from-to)	3747-3757
Journal	Tetrahedron Asymmetry
Volume	11
Issue number	18
DOIs	https://doi.org/10.1016/S0957-4166(00)00334-7
Publication status	Published - 22 Sep 2000

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title = "Preparation of enantiomers of 1-(1-naphthyl)-2,2-dimethylpropylamine and their behaviour as chiral solvating agents: Study of diastereochemic association by Job's plots and intermolecular NOE measurements",

abstract = "Enantiomers of 1-(1-naphthyl)-2,2-dimethylpropylamine have been obtained and considered as chiral solvating agents against several compounds. The formed complexes have been studied with the aid of the nuclear Overhauser effect and its stoichiometry by the method of continuous variations. Two diastereoisomeric complexes present similar geometry of association by π-π-stacking of the aromatic rings and by hydrogen bonding of the functional groups. {\textcopyright} 2000 Elsevier Science Ltd.",

author = "A. Port and A. Virgili and Alvarez-Larena, {A. Alvarez} and Piniella, {J. F.}",

year = "2000",

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day = "22",

doi = "10.1016/S0957-4166(00)00334-7",

language = "English",

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pages = "3747--3757",

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Preparation of enantiomers of 1-(1-naphthyl)-2,2-dimethylpropylamine and their behaviour as chiral solvating agents: Study of diastereochemic association by Job's plots and intermolecular NOE measurements. / Port, A.; Virgili, A.; Alvarez-Larena, A. Alvarez; Piniella, J. F.

In: Tetrahedron Asymmetry, Vol. 11, No. 18, 22.09.2000, p. 3747-3757.

Research output: Contribution to journal › Article › Research › peer-review

TY - JOUR

T1 - Preparation of enantiomers of 1-(1-naphthyl)-2,2-dimethylpropylamine and their behaviour as chiral solvating agents: Study of diastereochemic association by Job's plots and intermolecular NOE measurements

AU - Port, A.

AU - Virgili, A.

AU - Alvarez-Larena, A. Alvarez

AU - Piniella, J. F.

PY - 2000/9/22

Y1 - 2000/9/22

N2 - Enantiomers of 1-(1-naphthyl)-2,2-dimethylpropylamine have been obtained and considered as chiral solvating agents against several compounds. The formed complexes have been studied with the aid of the nuclear Overhauser effect and its stoichiometry by the method of continuous variations. Two diastereoisomeric complexes present similar geometry of association by π-π-stacking of the aromatic rings and by hydrogen bonding of the functional groups. © 2000 Elsevier Science Ltd.

AB - Enantiomers of 1-(1-naphthyl)-2,2-dimethylpropylamine have been obtained and considered as chiral solvating agents against several compounds. The formed complexes have been studied with the aid of the nuclear Overhauser effect and its stoichiometry by the method of continuous variations. Two diastereoisomeric complexes present similar geometry of association by π-π-stacking of the aromatic rings and by hydrogen bonding of the functional groups. © 2000 Elsevier Science Ltd.

U2 - 10.1016/S0957-4166(00)00334-7

DO - 10.1016/S0957-4166(00)00334-7

M3 - Article

VL - 11

SP - 3747

EP - 3757

IS - 18

ER -