Preparation of (1R,1′R)-1,1′-(anthracene-9,10-diyl)bis(2,2,2-trifluoroethanamine): a chiral diamine with low basicity

Carla Estivill, Julen Mendizabal, Albert Virgili, Eva Monteagudo, Teresa Flor, Francisco Sánchez-Ferrando, Angel Alvarez-Larena, Juan F. Piniella

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12 Citations (Scopus)

Abstract

A new chiral diamine with low basicity was synthesized in enantiopure form. (1R,1′R)-1,1′-(Anthracene-9,10-diyl)bis(2,2,2-trifluoroethanamine) was obtained by means of several stereochemically controlled reactions. The structures of the title compound and several intermediates were studied. © 2008 Elsevier Ltd. All rights reserved.
Original languageEnglish
Pages (from-to)171-176
JournalTetrahedron
Volume65
DOIs
Publication statusPublished - 3 Jan 2009

Keywords

  • Anthracene
  • Diamines
  • Enantiorecognition
  • α-Trifluoromethylamines

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