Preparation of (1R,1′R)-1,1′-(anthracene-9,10-diyl)bis(2,2,2-trifluoroethanamine): a chiral diamine with low basicity

Carla Estivill; Julen Mendizabal; Albert Virgili; Eva Monteagudo; Teresa Flor; Francisco Sánchez-Ferrando; Angel Alvarez-Larena; Juan F. Piniella

doi:https://doi.org/10.1016/j.tet.2008.10.082

Preparation of (1R,1′R)-1,1′-(anthracene-9,10-diyl)bis(2,2,2-trifluoroethanamine): a chiral diamine with low basicity

Carla Estivill, Julen Mendizabal, Albert Virgili, Eva Monteagudo, Teresa Flor, Francisco Sánchez-Ferrando, Angel Alvarez-Larena, Juan F. Piniella

Research output: Contribution to journal › Article › Research › peer-review

12 Citations (Scopus)

Abstract

A new chiral diamine with low basicity was synthesized in enantiopure form. (1R,1′R)-1,1′-(Anthracene-9,10-diyl)bis(2,2,2-trifluoroethanamine) was obtained by means of several stereochemically controlled reactions. The structures of the title compound and several intermediates were studied. © 2008 Elsevier Ltd. All rights reserved.

Original language	English
Pages (from-to)	171-176
Journal	Tetrahedron
Volume	65
DOIs	https://doi.org/10.1016/j.tet.2008.10.082
Publication status	Published - 3 Jan 2009

Keywords

Anthracene
Diamines
Enantiorecognition
α-Trifluoromethylamines

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title = "Preparation of (1R,1′R)-1,1′-(anthracene-9,10-diyl)bis(2,2,2-trifluoroethanamine): a chiral diamine with low basicity",

abstract = "A new chiral diamine with low basicity was synthesized in enantiopure form. (1R,1′R)-1,1′-(Anthracene-9,10-diyl)bis(2,2,2-trifluoroethanamine) was obtained by means of several stereochemically controlled reactions. The structures of the title compound and several intermediates were studied. {\textcopyright} 2008 Elsevier Ltd. All rights reserved.",

keywords = "Anthracene, Diamines, Enantiorecognition, α-Trifluoromethylamines",

author = "Carla Estivill and Julen Mendizabal and Albert Virgili and Eva Monteagudo and Teresa Flor and Francisco S{\'a}nchez-Ferrando and Angel Alvarez-Larena and Piniella, {Juan F.}",

year = "2009",

month = jan,

day = "3",

doi = "https://doi.org/10.1016/j.tet.2008.10.082",

language = "English",

volume = "65",

pages = "171--176",

journal = "Tetrahedron",

issn = "0040-4020",

publisher = "Elsevier Limited",

}

Preparation of (1R,1′R)-1,1′-(anthracene-9,10-diyl)bis(2,2,2-trifluoroethanamine): a chiral diamine with low basicity. / Estivill, Carla; Mendizabal, Julen; Virgili, Albert; Monteagudo, Eva; Flor, Teresa; Sánchez-Ferrando, Francisco; Alvarez-Larena, Angel; Piniella, Juan F.

In: Tetrahedron, Vol. 65, 03.01.2009, p. 171-176.

Research output: Contribution to journal › Article › Research › peer-review

TY - JOUR

T1 - Preparation of (1R,1′R)-1,1′-(anthracene-9,10-diyl)bis(2,2,2-trifluoroethanamine): a chiral diamine with low basicity

AU - Estivill, Carla

AU - Mendizabal, Julen

AU - Virgili, Albert

AU - Monteagudo, Eva

AU - Flor, Teresa

AU - Sánchez-Ferrando, Francisco

AU - Alvarez-Larena, Angel

AU - Piniella, Juan F.

PY - 2009/1/3

Y1 - 2009/1/3

N2 - A new chiral diamine with low basicity was synthesized in enantiopure form. (1R,1′R)-1,1′-(Anthracene-9,10-diyl)bis(2,2,2-trifluoroethanamine) was obtained by means of several stereochemically controlled reactions. The structures of the title compound and several intermediates were studied. © 2008 Elsevier Ltd. All rights reserved.

AB - A new chiral diamine with low basicity was synthesized in enantiopure form. (1R,1′R)-1,1′-(Anthracene-9,10-diyl)bis(2,2,2-trifluoroethanamine) was obtained by means of several stereochemically controlled reactions. The structures of the title compound and several intermediates were studied. © 2008 Elsevier Ltd. All rights reserved.

KW - Anthracene

KW - Diamines

KW - Enantiorecognition

KW - α-Trifluoromethylamines

U2 - https://doi.org/10.1016/j.tet.2008.10.082

DO - https://doi.org/10.1016/j.tet.2008.10.082

M3 - Article

VL - 65

SP - 171

EP - 176

JO - Tetrahedron

JF - Tetrahedron

SN - 0040-4020

ER -