Preparation and X-ray crystal structure of [Ni6 {μ-S(CH2)3 N(CH3)2}12], a cyclic hexameric homothiolate of nickel

Mercè Capdevila; Pilar González-Duarte; Joan Sola; Concha Foces-Foces; Félix Hernández Cano; Martín Martínez-Ripoll

doi:10.1016/S0277-5387(00)86522-5

Preparation and X-ray crystal structure of [Ni₆{μ-S(CH₂)₃N(CH₃)₂}₁₂], a cyclic hexameric homothiolate of nickel

Mercè Capdevila, Pilar González-Duarte, Joan Sola, Concha Foces-Foces, Félix Hernández Cano, Martín Martínez-Ripoll

Department of Chemistry

Research output: Contribution to journal › Article › Research › peer-review

28 Citations (Scopus)

Abstract

Highly hygroscopic, black, prism-like crystals separated out from CH3CN solutions containing (Et4N)2NiCl4 and 3-dimethylamino-1-propanethiol at several mole ratios. Crystals of [Ni6{S(CH2)3N(CH3)2}12] are orthorhombic, space group P21212 with a = 30.197(6), b = 29.231(4), c = 10.649(1) Å and Z = 4. The Ni6S12 core of each molecular unit constitutes a hexagonal prism whose rectangular faces are NiS4 coordination planes (NiS = 2.19 Å; SNiS = 82.2°, 98.05°). Approximate diameters for the Ni6 and S6 rings are 5.85 and 6.60 Å, respectively. The allowed molecular symmetry for the Ni6S12 core, D6h, is reduced to D3d when the axial and equatorial SC bonds are included. © 1989.

Original language	English
Pages (from-to)	1253-1259
Journal	Polyhedron
Volume	8
Issue number	10
DOIs	https://doi.org/10.1016/S0277-5387(00)86522-5
Publication status	Published - 1 Jan 1989

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@article{bf51e0a2f7b641fe8260e1fa59896c5a,

title = "Preparation and X-ray crystal structure of [Ni6 {μ-S(CH2)3 N(CH3)2}12], a cyclic hexameric homothiolate of nickel",

abstract = "Highly hygroscopic, black, prism-like crystals separated out from CH3CN solutions containing (Et4N)2NiCl4 and 3-dimethylamino-1-propanethiol at several mole ratios. Crystals of [Ni6{S(CH2)3N(CH3)2}12] are orthorhombic, space group P21212 with a = 30.197(6), b = 29.231(4), c = 10.649(1) {\AA} and Z = 4. The Ni6S12 core of each molecular unit constitutes a hexagonal prism whose rectangular faces are NiS4 coordination planes (NiS = 2.19 {\AA}; SNiS = 82.2°, 98.05°). Approximate diameters for the Ni6 and S6 rings are 5.85 and 6.60 {\AA}, respectively. The allowed molecular symmetry for the Ni6S12 core, D6h, is reduced to D3d when the axial and equatorial SC bonds are included. {\textcopyright} 1989.",

author = "Merc{\`e} Capdevila and Pilar Gonz{\'a}lez-Duarte and Joan Sola and Concha Foces-Foces and Cano, {F{\'e}lix Hern{\'a}ndez} and Mart{\'i}n Mart{\'i}nez-Ripoll",

year = "1989",

month = jan,

day = "1",

doi = "10.1016/S0277-5387(00)86522-5",

language = "English",

volume = "8",

pages = "1253--1259",

journal = "Polyhedron",

issn = "0277-5387",

publisher = "Elsevier Limited",

number = "10",

}

Preparation and X-ray crystal structure of [Ni₆{μ-S(CH₂)₃N(CH₃)₂}₁₂], a cyclic hexameric homothiolate of nickel. / Capdevila, Mercè; González-Duarte, Pilar; Sola, Joan; Foces-Foces, Concha; Cano, Félix Hernández; Martínez-Ripoll, Martín.

In: Polyhedron, Vol. 8, No. 10, 01.01.1989, p. 1253-1259.

Research output: Contribution to journal › Article › Research › peer-review

TY - JOUR

T1 - Preparation and X-ray crystal structure of [Ni6 {μ-S(CH2)3 N(CH3)2}12], a cyclic hexameric homothiolate of nickel

AU - Capdevila, Mercè

AU - González-Duarte, Pilar

AU - Sola, Joan

AU - Foces-Foces, Concha

AU - Cano, Félix Hernández

AU - Martínez-Ripoll, Martín

PY - 1989/1/1

Y1 - 1989/1/1

N2 - Highly hygroscopic, black, prism-like crystals separated out from CH3CN solutions containing (Et4N)2NiCl4 and 3-dimethylamino-1-propanethiol at several mole ratios. Crystals of [Ni6{S(CH2)3N(CH3)2}12] are orthorhombic, space group P21212 with a = 30.197(6), b = 29.231(4), c = 10.649(1) Å and Z = 4. The Ni6S12 core of each molecular unit constitutes a hexagonal prism whose rectangular faces are NiS4 coordination planes (NiS = 2.19 Å; SNiS = 82.2°, 98.05°). Approximate diameters for the Ni6 and S6 rings are 5.85 and 6.60 Å, respectively. The allowed molecular symmetry for the Ni6S12 core, D6h, is reduced to D3d when the axial and equatorial SC bonds are included. © 1989.

AB - Highly hygroscopic, black, prism-like crystals separated out from CH3CN solutions containing (Et4N)2NiCl4 and 3-dimethylamino-1-propanethiol at several mole ratios. Crystals of [Ni6{S(CH2)3N(CH3)2}12] are orthorhombic, space group P21212 with a = 30.197(6), b = 29.231(4), c = 10.649(1) Å and Z = 4. The Ni6S12 core of each molecular unit constitutes a hexagonal prism whose rectangular faces are NiS4 coordination planes (NiS = 2.19 Å; SNiS = 82.2°, 98.05°). Approximate diameters for the Ni6 and S6 rings are 5.85 and 6.60 Å, respectively. The allowed molecular symmetry for the Ni6S12 core, D6h, is reduced to D3d when the axial and equatorial SC bonds are included. © 1989.

U2 - 10.1016/S0277-5387(00)86522-5

DO - 10.1016/S0277-5387(00)86522-5

M3 - Article

VL - 8

SP - 1253

EP - 1259

JO - Polyhedron

JF - Polyhedron

SN - 0277-5387

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