Preparation and crystal structure of the unprecedented octameric zinc-aminothiolate complex [Zn<inf>8</inf>{S(CH<inf>2</inf>)<inf>3</inf>NMe <inf>2</inf>}<inf>16</inf>]

Isidre Casals; William Clegg; Pilar González-Duarte

doi:10.1039/C39910000655

Preparation and crystal structure of the unprecedented octameric zinc-aminothiolate complex [Zn<inf>8</inf>{S(CH<inf>2</inf>)<inf>3</inf>NMe <inf>2</inf>}<inf>16</inf>]

Isidre Casals, William Clegg, Pilar González-Duarte

Department of Chemistry

Research output: Contribution to journal › Article › Research › peer-review

15 Citations (Scopus)

Abstract

[Zn8{S(CH2)3NMe2} 16], prepared by anodic oxidation of zinc in acetonitrile containing 3-dimethylamino-1-propanethiol, contains zinc atoms coordinated tetrahedrally by either four sulphur or one nitrogen and three sulphur atoms; the aminothiolate ligands function variously as terminal, μ2-bridging, or both chelating and bridging ligands.

Original language	English
Pages (from-to)	655-656
Journal	Journal of the Chemical Society D: Chemical Communications
Issue number	9
DOIs	https://doi.org/10.1039/C39910000655
Publication status	Published - 1 Dec 1991

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title = "Preparation and crystal structure of the unprecedented octameric zinc-aminothiolate complex [Zn8{S(CH2)3NMe 2}16]",

abstract = "[Zn8{S(CH2)3NMe2} 16], prepared by anodic oxidation of zinc in acetonitrile containing 3-dimethylamino-1-propanethiol, contains zinc atoms coordinated tetrahedrally by either four sulphur or one nitrogen and three sulphur atoms; the aminothiolate ligands function variously as terminal, μ2-bridging, or both chelating and bridging ligands.",

author = "Isidre Casals and William Clegg and Pilar Gonz{\'a}lez-Duarte",

year = "1991",

month = dec,

day = "1",

doi = "10.1039/C39910000655",

language = "English",

pages = "655--656",

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}

Preparation and crystal structure of the unprecedented octameric zinc-aminothiolate complex [Zn<inf>8</inf>{S(CH<inf>2</inf>)<inf>3</inf>NMe <inf>2</inf>}<inf>16</inf>]. / Casals, Isidre; Clegg, William; González-Duarte, Pilar.

In: Journal of the Chemical Society D: Chemical Communications, No. 9, 01.12.1991, p. 655-656.

Research output: Contribution to journal › Article › Research › peer-review

TY - JOUR

T1 - Preparation and crystal structure of the unprecedented octameric zinc-aminothiolate complex [Zn8{S(CH2)3NMe 2}16]

AU - Casals, Isidre

AU - Clegg, William

AU - González-Duarte, Pilar

PY - 1991/12/1

Y1 - 1991/12/1

N2 - [Zn8{S(CH2)3NMe2} 16], prepared by anodic oxidation of zinc in acetonitrile containing 3-dimethylamino-1-propanethiol, contains zinc atoms coordinated tetrahedrally by either four sulphur or one nitrogen and three sulphur atoms; the aminothiolate ligands function variously as terminal, μ2-bridging, or both chelating and bridging ligands.

AB - [Zn8{S(CH2)3NMe2} 16], prepared by anodic oxidation of zinc in acetonitrile containing 3-dimethylamino-1-propanethiol, contains zinc atoms coordinated tetrahedrally by either four sulphur or one nitrogen and three sulphur atoms; the aminothiolate ligands function variously as terminal, μ2-bridging, or both chelating and bridging ligands.

U2 - 10.1039/C39910000655

DO - 10.1039/C39910000655

M3 - Article

SP - 655

EP - 656

IS - 9

ER -

Preparation and crystal structure of the unprecedented octameric zinc-aminothiolate complex [Zn<inf>8</inf>{S(CH<inf>2</inf>)<inf>3</inf>NMe <inf>2</inf>}<inf>16</inf>]

Abstract

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