Preparation and crystal structure of the unprecedented octameric zinc-aminothiolate complex [Zn<inf>8</inf>{S(CH<inf>2</inf>)<inf>3</inf>NMe <inf>2</inf>}<inf>16</inf>]

Isidre Casals, William Clegg, Pilar González-Duarte

Research output: Contribution to journalArticleResearchpeer-review

15 Citations (Scopus)

Abstract

[Zn8{S(CH2)3NMe2} 16], prepared by anodic oxidation of zinc in acetonitrile containing 3-dimethylamino-1-propanethiol, contains zinc atoms coordinated tetrahedrally by either four sulphur or one nitrogen and three sulphur atoms; the aminothiolate ligands function variously as terminal, μ2-bridging, or both chelating and bridging ligands.
Original languageEnglish
Pages (from-to)655-656
JournalJournal of the Chemical Society, Chemical Communications
Issue number9
DOIs
Publication statusPublished - 1 Dec 1991

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