Polymerization reactions in [Co(NH<inf>3</inf>)<inf>5</inf>(H<inf>2</inf>O)][CoX(CN)<inf>5</inf>] and cis-[Co(NH<inf>3</inf>)<inf>4</inf>(H<inf>2</inf>O)<inf>2</inf>][CoX(CN)<inf>5</inf>] (X = Cl, Br, I, No<inf>2</inf> OR N<inf>3</inf>) double-complex salts

T. Flor; J. Casabó

doi:10.1016/S0277-5387(00)80841-4

Polymerization reactions in [Co(NH<inf>3</inf>)<inf>5</inf>(H<inf>2</inf>O)][CoX(CN)<inf>5</inf>] and cis-[Co(NH<inf>3</inf>)<inf>4</inf>(H<inf>2</inf>O)<inf>2</inf>][CoX(CN)<inf>5</inf>] (X = Cl, Br, I, No<inf>2</inf> OR N<inf>3</inf>) double-complex salts

T. Flor, J. Casabó

Department of Chemistry

Research output: Contribution to journal › Article › Research › peer-review

1 Citation (Scopus)

Abstract

Polymerization reactions of [Co(NH3)5(H2O)][CoX(CN)5] and cis-[Co(NH3)4 (H2O)2][CoX(CN)5] (X = Cl, Br, I, NO2 or N3] have been studied. The compounds undergo aging reactions in the solid state or in solution induced by the ligand X involving solvolytic processes affording polymeric materials with μ-cyano bridges. A mechanistic explanation of these reactions is given and a comparison between both series of compounds together with the parent compound [Co(NH3)6][Co(CN)6] is discussed. © 1987.

Original language	English
Pages (from-to)	1563-1569
Journal	Polyhedron
Volume	6
Issue number	7
DOIs	https://doi.org/10.1016/S0277-5387(00)80841-4
Publication status	Published - 1 Jan 1987

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@article{5ce449d100454ddaa9f52b77de7dd220,

title = "Polymerization reactions in [Co(NH3)5(H2O)][CoX(CN)5] and cis-[Co(NH3)4(H2O)2][CoX(CN)5] (X = Cl, Br, I, No2 OR N3) double-complex salts",

abstract = "Polymerization reactions of [Co(NH3)5(H2O)][CoX(CN)5] and cis-[Co(NH3)4 (H2O)2][CoX(CN)5] (X = Cl, Br, I, NO2 or N3] have been studied. The compounds undergo aging reactions in the solid state or in solution induced by the ligand X involving solvolytic processes affording polymeric materials with μ-cyano bridges. A mechanistic explanation of these reactions is given and a comparison between both series of compounds together with the parent compound [Co(NH3)6][Co(CN)6] is discussed. {\textcopyright} 1987.",

author = "T. Flor and J. Casab{\'o}",

year = "1987",

month = jan,

day = "1",

doi = "10.1016/S0277-5387(00)80841-4",

language = "English",

volume = "6",

pages = "1563--1569",

journal = "Polyhedron",

issn = "0277-5387",

publisher = "Elsevier Limited",

number = "7",

}

Flor, T & Casabó, J 1987, 'Polymerization reactions in [Co(NH<inf>3</inf>)<inf>5</inf>(H<inf>2</inf>O)][CoX(CN)<inf>5</inf>] and cis-[Co(NH<inf>3</inf>)<inf>4</inf>(H<inf>2</inf>O)<inf>2</inf>][CoX(CN)<inf>5</inf>] (X = Cl, Br, I, No<inf>2</inf> OR N<inf>3</inf>) double-complex salts', Polyhedron, vol. 6, no. 7, pp. 1563-1569. https://doi.org/10.1016/S0277-5387(00)80841-4

Polymerization reactions in [Co(NH<inf>3</inf>)<inf>5</inf>(H<inf>2</inf>O)][CoX(CN)<inf>5</inf>] and cis-[Co(NH<inf>3</inf>)<inf>4</inf>(H<inf>2</inf>O)<inf>2</inf>][CoX(CN)<inf>5</inf>] (X = Cl, Br, I, No<inf>2</inf> OR N<inf>3</inf>) double-complex salts. / Flor, T.; Casabó, J.

In: Polyhedron, Vol. 6, No. 7, 01.01.1987, p. 1563-1569.

Research output: Contribution to journal › Article › Research › peer-review

TY - JOUR

T1 - Polymerization reactions in [Co(NH3)5(H2O)][CoX(CN)5] and cis-[Co(NH3)4(H2O)2][CoX(CN)5] (X = Cl, Br, I, No2 OR N3) double-complex salts

AU - Flor, T.

AU - Casabó, J.

PY - 1987/1/1

Y1 - 1987/1/1

N2 - Polymerization reactions of [Co(NH3)5(H2O)][CoX(CN)5] and cis-[Co(NH3)4 (H2O)2][CoX(CN)5] (X = Cl, Br, I, NO2 or N3] have been studied. The compounds undergo aging reactions in the solid state or in solution induced by the ligand X involving solvolytic processes affording polymeric materials with μ-cyano bridges. A mechanistic explanation of these reactions is given and a comparison between both series of compounds together with the parent compound [Co(NH3)6][Co(CN)6] is discussed. © 1987.

AB - Polymerization reactions of [Co(NH3)5(H2O)][CoX(CN)5] and cis-[Co(NH3)4 (H2O)2][CoX(CN)5] (X = Cl, Br, I, NO2 or N3] have been studied. The compounds undergo aging reactions in the solid state or in solution induced by the ligand X involving solvolytic processes affording polymeric materials with μ-cyano bridges. A mechanistic explanation of these reactions is given and a comparison between both series of compounds together with the parent compound [Co(NH3)6][Co(CN)6] is discussed. © 1987.

U2 - 10.1016/S0277-5387(00)80841-4

DO - 10.1016/S0277-5387(00)80841-4

M3 - Article

VL - 6

SP - 1563

EP - 1569

JO - Polyhedron

JF - Polyhedron

SN - 0277-5387

IS - 7

ER -