TY - JOUR
T1 - Polymerization reactions in [Co(NH3)5(H2O)][CoX(CN)5] and cis-[Co(NH3)4(H2O)2][CoX(CN)5] (X = Cl, Br, I, No2 OR N3) double-complex salts
AU - Flor, T.
AU - Casabó, J.
PY - 1987/1/1
Y1 - 1987/1/1
N2 - Polymerization reactions of [Co(NH3)5(H2O)][CoX(CN)5] and cis-[Co(NH3)4 (H2O)2][CoX(CN)5] (X = Cl, Br, I, NO2 or N3] have been studied. The compounds undergo aging reactions in the solid state or in solution induced by the ligand X involving solvolytic processes affording polymeric materials with μ-cyano bridges. A mechanistic explanation of these reactions is given and a comparison between both series of compounds together with the parent compound [Co(NH3)6][Co(CN)6] is discussed. © 1987.
AB - Polymerization reactions of [Co(NH3)5(H2O)][CoX(CN)5] and cis-[Co(NH3)4 (H2O)2][CoX(CN)5] (X = Cl, Br, I, NO2 or N3] have been studied. The compounds undergo aging reactions in the solid state or in solution induced by the ligand X involving solvolytic processes affording polymeric materials with μ-cyano bridges. A mechanistic explanation of these reactions is given and a comparison between both series of compounds together with the parent compound [Co(NH3)6][Co(CN)6] is discussed. © 1987.
U2 - 10.1016/S0277-5387(00)80841-4
DO - 10.1016/S0277-5387(00)80841-4
M3 - Article
VL - 6
SP - 1563
EP - 1569
IS - 7
ER -