Photothermal Activation of Metal-Organic Frameworks Using a UV-Vis Light Source

Jordi Espín, Luis Garzón-Tovar, Arnau Carné-Sánchez, Inhar Imaz, Daniel Maspoch

    Research output: Contribution to journalArticleResearchpeer-review

    26 Citations (Scopus)

    Abstract

    © 2018 American Chemical Society. Metal-organic frameworks (MOFs) usually require meticulous removal of the solvent molecules to unlock their potential porosity. Herein, we report a novel one-step method for activating MOFs based on the photothermal effect induced by directly irradiating them with a UV-vis lamp. The localized light-to-heat conversion produced in the MOF crystals upon irradiation enables a very fast solvent removal, thereby significantly reducing the activation time to as low as 30 min and suppressing the need for time-consuming solvent-exchange procedures and vacuum conditions. This approach is successful for a broad range of MOFs, including HKUST-1, UiO-66-NH2, ZIF-67, CPO-27-M (M = Zn, Ni, and Mg), Fe-MIL-101-NH2, and IRMOF-3, all of which exhibit absorption bands in the light emission range. In addition, we anticipate that this photothermal activation can also be used to activate covalent organic frameworks (COFs).
    Original languageEnglish
    Pages (from-to)9555-9562
    JournalACS applied materials & interfaces
    Volume10
    Issue number11
    DOIs
    Publication statusPublished - 21 Mar 2018

    Keywords

    • UV-vis light
    • activation
    • metal-organic framework
    • permanent porosity
    • photothermal effect

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