Phosphine/Sulfoxide-Supported Carbon(0) Complex

Mariana Lozano González, Laura Bousquet, Sophie Hameury, Cecilio Alvarez Toledano, Nathalie Saffon-Merceron, Vicenç Branchadell, Eddy Maerten, Antoine Baceiredo

Research output: Contribution to journalArticleResearchpeer-review

5 Citations (Scopus)

Abstract

© 2018 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim A new carbon(0) complex 2 with two different L ligands, a phosphine and a sulfoxide, was synthesized and fully characterized. This new type of carbone exhibits excellent coordination ability, in contrast to the related phosphine/sulfide-supported carbon(0) complexes. Several organometallic complexes were isolated and, of special interest, the νav(CO) value of RhI-dicarbonyl complex indicates that 2 has a donor capability superior to classical NHCs.
Original languageEnglish
Pages (from-to)2570-2574
JournalChemistry - A European Journal
Volume24
Issue number11
DOIs
Publication statusPublished - 21 Feb 2018

Keywords

  • carbon(0) complexes
  • ligand
  • phosphine
  • sulfoxide
  • σ-donor

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