Phosphines exchange in quadruply bonded metal dimers: Theoretical proposal for an alternative to the internal flip mechanism

Yves Jean, Agusti Lledos

Research output: Contribution to journalArticleResearchpeer-review

9 Citations (Scopus)

Abstract

The non-concerted jumping of two phosphine ligands from one metal center to the other in [Mo2Cl4(PH3)4] is found to be < 30 kcal mol-1 (1 cal = 4.184 J) energy costing process (DFT calculations).
Original languageEnglish
Pages (from-to)1443-1444
JournalChemical Communications
Issue number14
DOIs
Publication statusPublished - 21 Jul 1998

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