Perfluoro-tagged rhodium and ruthenium nanoparticles immobilized on silica gel as highly active catalysts for hydrogenation of arenes under mild conditions

Sandra Niembro, Silvia Donnici, Alexandr Shafir, Adelina Vallribera, María L. Buil, Miguel A. Esteruelas, Carmen Larramona

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20 Citations (Scopus)

Abstract

Perfluoro-tagged rhodium and ruthenium nanoparticles have been stabilized on highly fluorinated hybrid organic-inorganic silica gel. The method for preparation of these nanoparticles is highly reproducible and the new materials were robust, recoverable and active catalysts for arene hydrogenation under very mild conditions. © 2012 The Royal Society of Chemistry and the Centre National de la Recherche Scientifique.
Original languageEnglish
Pages (from-to)278-282
JournalNew Journal of Chemistry
Volume37
Issue number2
DOIs
Publication statusPublished - 1 Feb 2013

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    Niembro, S., Donnici, S., Shafir, A., Vallribera, A., Buil, M. L., Esteruelas, M. A., & Larramona, C. (2013). Perfluoro-tagged rhodium and ruthenium nanoparticles immobilized on silica gel as highly active catalysts for hydrogenation of arenes under mild conditions. New Journal of Chemistry, 37(2), 278-282. https://doi.org/10.1039/c2nj40859g