PEGPHOT: A new well-defined molecular weight polyether-substituted triphenylphosphite and its application in biphasic hydroformylation

José Ribeiro Gregório; Ricardo Gomes Da Rosa; Ana Néry Furlan Mendes; Joan Carles Bayón

doi:10.1007/s10562-011-0603-5

PEGPHOT: A new well-defined molecular weight polyether-substituted triphenylphosphite and its application in biphasic hydroformylation

José Ribeiro Gregório, Ricardo Gomes Da Rosa, Ana Néry Furlan Mendes, Joan Carles Bayón

Department of Chemistry

Research output: Contribution to journal › Article › Research › peer-review

5 Citations (Scopus)

Abstract

This work describes the synthesis and characterization of PEGPHOT (tri-(4-triethylenoglycol-monomethyletherphenyl)phosphite) and its use in the rhodium-catalyzed hydroformylation of different olefins. In the hydroformylation of 1-hexene, it was possible to carry out 10 recycles of the catalytic system without significant loss in activity. © 2011 Springer Science+Business Media, LLC.

Original language	English
Pages (from-to)	977-981
Journal	Catalysis Letters
Volume	141
Issue number	7
DOIs	https://doi.org/10.1007/s10562-011-0603-5
Publication status	Published - 1 Jul 2011

Keywords

Biphasic catalytic system
Hydroformylation
PEG
PEO
Rhodium

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10.1007/s10562-011-0603-5

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abstract = "This work describes the synthesis and characterization of PEGPHOT (tri-(4-triethylenoglycol-monomethyletherphenyl)phosphite) and its use in the rhodium-catalyzed hydroformylation of different olefins. In the hydroformylation of 1-hexene, it was possible to carry out 10 recycles of the catalytic system without significant loss in activity. {\textcopyright} 2011 Springer Science+Business Media, LLC.",

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AU - Gregório, José Ribeiro

AU - Da Rosa, Ricardo Gomes

AU - Mendes, Ana Néry Furlan

AU - Bayón, Joan Carles

PY - 2011/7/1

Y1 - 2011/7/1

N2 - This work describes the synthesis and characterization of PEGPHOT (tri-(4-triethylenoglycol-monomethyletherphenyl)phosphite) and its use in the rhodium-catalyzed hydroformylation of different olefins. In the hydroformylation of 1-hexene, it was possible to carry out 10 recycles of the catalytic system without significant loss in activity. © 2011 Springer Science+Business Media, LLC.

AB - This work describes the synthesis and characterization of PEGPHOT (tri-(4-triethylenoglycol-monomethyletherphenyl)phosphite) and its use in the rhodium-catalyzed hydroformylation of different olefins. In the hydroformylation of 1-hexene, it was possible to carry out 10 recycles of the catalytic system without significant loss in activity. © 2011 Springer Science+Business Media, LLC.

KW - Biphasic catalytic system

KW - Hydroformylation

KW - PEG

KW - PEO

KW - Rhodium

U2 - 10.1007/s10562-011-0603-5

DO - 10.1007/s10562-011-0603-5

M3 - Article

SN - 1011-372X

VL - 141

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JO - Catalysis Letters

JF - Catalysis Letters

IS - 7

ER -

PEGPHOT: A new well-defined molecular weight polyether-substituted triphenylphosphite and its application in biphasic hydroformylation

Abstract

Keywords

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