Palladium(II) complexes with Pd<inf>2</inf>S<inf>2</inf> rings. Synthesis and theoretical characterization of [Pd<inf>2</inf>(dppe)<inf>2</inf>(μ-S)<inf>2</inf>] and X-ray characterization of [Pd<inf>3</inf>(dppe)<inf>3</inf>(μ<inf>3</inf>-S)<inf>2</inf>]Cl<inf>2</inf>

Mercè Capdevila, William Clegg, Robert A. Coxall, Pilar González-Duarte, Mohamed Hamidi, Agustí Lledós, Gregori Ujaque

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14 Citations (Scopus)

Abstract

The use of the dppe ligand and the fine tuning of the experimental conditions has allowed isolation of [Pd2(dppe)2) (μ-S)2], whose structural characterization has been achieved by ab initio MP2 calculations, and of [Pd3(dppe)3(μ3-S)2]Cl 2, the X-ray structure of which is also reported. © 1998 Elsevier Science S.A. All rights reserved.
Original languageEnglish
Pages (from-to)466-468
JournalInorganic Chemistry Communications
Volume1
Issue number12
DOIs
Publication statusPublished - 1 Jan 1998

Keywords

  • Crystal structures
  • Platinum complexes
  • Sulfide complexes
  • Theoretical calculations

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