Palladium(II) complexes with Pd2 S2 rings. Synthesis and theoretical characterization of [Pd2 (dppe)2(μ-S)2] and X-ray Characterization of [Pd3(dppe)3 (μ3\-S)2 ] CI2

Mercè Capdevila; William Clegg; Robert A. Coxall; Pilar González-Duarte; Mohamed Hamidi; Agustí Lledós; Gregori Ujaque

doi:10.1016/S1387-7003(98)00125-7

Palladium(II) complexes with Pd₂ S₂ rings. Synthesis and theoretical characterization of [Pd₂ (dppe)₂(μ-S)₂] and X-ray Characterization of [Pd₃(dppe)₃(μ₃\-S)₂ ] CI₂

Mercè Capdevila, William Clegg, Robert A. Coxall, Pilar González-Duarte, Mohamed Hamidi, Agustí Lledós, Gregori Ujaque

Department of Chemistry

Research output: Contribution to journal › Article › Research › peer-review

16 Citations (Scopus)

Abstract

The use of the dppe ligand and the fine tuning of the experimental conditions has allowed isolation of [Pd2(dppe)2) (μ-S)2], whose structural characterization has been achieved by ab initio MP2 calculations, and of [Pd3(dppe)3(μ3-S)2]Cl 2, the X-ray structure of which is also reported. © 1998 Elsevier Science S.A. All rights reserved.

Original language	English
Pages (from-to)	466-468
Journal	Inorganic Chemistry Communications
Volume	1
Issue number	12
DOIs	https://doi.org/10.1016/S1387-7003(98)00125-7
Publication status	Published - 1 Jan 1998

Keywords

Crystal structures
Platinum complexes
Sulfide complexes
Theoretical calculations

Access to Document

10.1016/S1387-7003(98)00125-7

CCDC 119508: Experimental Crystal Structure Determination
Capdevila Vidal, M. M. (Creator), Clegg, W. (Creator), Coxall, R. A. (Creator), González-Duarte, P. (Contributor), Hamidi, M. (Creator), Lledos Falco, A. (Contributor) & Ujaque Perez, G. (Creator), Cambridge Crystallographic Data Centre, 19 Nov 1999
DOI: 10.5517/cc40c3l, http://www.ccdc.cam.ac.uk/services/structure_request?id=doi:10.5517/cc40c3l&sid=DataCite
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Capdevila, M., Clegg, W., Coxall, R. A., González-Duarte, P., Hamidi, M., Lledós, A., & Ujaque, G. (1998). Palladium(II) complexes with Pd₂ S₂ rings. Synthesis and theoretical characterization of [Pd₂ (dppe)₂(μ-S)₂] and X-ray Characterization of [Pd₃(dppe)₃(μ₃\-S)₂ ] CI₂. Inorganic Chemistry Communications, 1(12), 466-468. https://doi.org/10.1016/S1387-7003(98)00125-7

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title = "Palladium(II) complexes with Pd2 S2 rings. Synthesis and theoretical characterization of [Pd2 (dppe)2(μ-S)2] and X-ray Characterization of [Pd3(dppe)3 (μ3\-S)2 ] CI2",

abstract = "The use of the dppe ligand and the fine tuning of the experimental conditions has allowed isolation of [Pd2(dppe)2) (μ-S)2], whose structural characterization has been achieved by ab initio MP2 calculations, and of [Pd3(dppe)3(μ3-S)2]Cl 2, the X-ray structure of which is also reported. {\textcopyright} 1998 Elsevier Science S.A. All rights reserved.",

keywords = "Crystal structures, Platinum complexes, Sulfide complexes, Theoretical calculations",

author = "Merc{\`e} Capdevila and William Clegg and Coxall, {Robert A.} and Pilar Gonz{\'a}lez-Duarte and Mohamed Hamidi and Agust{\'i} Lled{\'o}s and Gregori Ujaque",

year = "1998",

month = jan,

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doi = "10.1016/S1387-7003(98)00125-7",

language = "English",

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pages = "466--468",

journal = "Inorganic Chemistry Communications",

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Capdevila, M, Clegg, W, Coxall, RA, González-Duarte, P, Hamidi, M, Lledós, A & Ujaque, G 1998, 'Palladium(II) complexes with Pd₂ S₂ rings. Synthesis and theoretical characterization of [Pd₂ (dppe)₂(μ-S)₂] and X-ray Characterization of [Pd₃(dppe)₃(μ₃\-S)₂ ] CI₂', Inorganic Chemistry Communications, vol. 1, no. 12, pp. 466-468. https://doi.org/10.1016/S1387-7003(98)00125-7

Palladium(II) complexes with Pd₂ S₂ rings. Synthesis and theoretical characterization of [Pd₂ (dppe)₂(μ-S)₂] and X-ray Characterization of [Pd₃(dppe)₃(μ₃\-S)₂ ] CI₂. / Capdevila, Mercè; Clegg, William; Coxall, Robert A. et al.
In: Inorganic Chemistry Communications, Vol. 1, No. 12, 01.01.1998, p. 466-468.

Research output: Contribution to journal › Article › Research › peer-review

TY - JOUR

T1 - Palladium(II) complexes with Pd2 S2 rings. Synthesis and theoretical characterization of [Pd2 (dppe)2(μ-S)2] and X-ray Characterization of [Pd3(dppe)3 (μ3\-S)2 ] CI2

AU - Capdevila, Mercè

AU - Clegg, William

AU - Coxall, Robert A.

AU - González-Duarte, Pilar

AU - Hamidi, Mohamed

AU - Lledós, Agustí

AU - Ujaque, Gregori

PY - 1998/1/1

Y1 - 1998/1/1

N2 - The use of the dppe ligand and the fine tuning of the experimental conditions has allowed isolation of [Pd2(dppe)2) (μ-S)2], whose structural characterization has been achieved by ab initio MP2 calculations, and of [Pd3(dppe)3(μ3-S)2]Cl 2, the X-ray structure of which is also reported. © 1998 Elsevier Science S.A. All rights reserved.

AB - The use of the dppe ligand and the fine tuning of the experimental conditions has allowed isolation of [Pd2(dppe)2) (μ-S)2], whose structural characterization has been achieved by ab initio MP2 calculations, and of [Pd3(dppe)3(μ3-S)2]Cl 2, the X-ray structure of which is also reported. © 1998 Elsevier Science S.A. All rights reserved.

KW - Crystal structures

KW - Platinum complexes

KW - Sulfide complexes

KW - Theoretical calculations

U2 - 10.1016/S1387-7003(98)00125-7

DO - 10.1016/S1387-7003(98)00125-7

M3 - Article

SN - 1387-7003

VL - 1

SP - 466

EP - 468

JO - Inorganic Chemistry Communications

JF - Inorganic Chemistry Communications

IS - 12

ER -

Palladium(II) complexes with Pd2 S2 rings. Synthesis and theoretical characterization of [Pd2 (dppe)2(μ-S)2] and X-ray Characterization of [Pd3(dppe)3 (μ3\-S)2 ] CI2

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CCDC 119508: Experimental Crystal Structure Determination

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Palladium(II) complexes with Pd₂ S₂ rings. Synthesis and theoretical characterization of [Pd₂ (dppe)₂(μ-S)₂] and X-ray Characterization of [Pd₃(dppe)₃(μ₃\-S)₂ ] CI₂