Palladium nanoparticles supported on an organic-inorganic fluorinated hybrid material. Application to microwave-based Heck reaction

Sandra Niembro; Alexandr Shafir; Adelina Vallribera; Ramon Alibés

doi:10.1021/ol801091u

Palladium nanoparticles supported on an organic-inorganic fluorinated hybrid material. Application to microwave-based Heck reaction

Sandra Niembro, Alexandr Shafir, Adelina Vallribera, Ramon Alibés

Department of Chemistry

Research output: Contribution to journal › Article › Research › peer-review

80 Citations (Scopus)

Abstract

(Chemical Equation Presented) Phosphine-free palladium nanoparticles were embedded in a fluorous organic-inorganic hybrid material 6b prepared by the sol-gel process. The use of Pdn·6b in the Heck coupling reaction under microwave irradiation has been investigated. Recycling studies have shown that the catalyst can be readily recovered and reused several times without significant loss of activity. Reactions and recovery of the solid-supported palladium catalyst system can be carried out in the presence of air, without any particular precaution. © 2008 American Chemical Society.

Original language	English
Pages (from-to)	3215-3218
Journal	Organic Letters
Volume	10
Issue number	15
DOIs	https://doi.org/10.1021/ol801091u
Publication status	Published - 1 Dec 2008

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10.1021/ol801091u

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Niembro, S., Shafir, A., Vallribera, A., & Alibés, R. (2008). Palladium nanoparticles supported on an organic-inorganic fluorinated hybrid material. Application to microwave-based Heck reaction. Organic Letters, 10(15), 3215-3218. https://doi.org/10.1021/ol801091u

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abstract = "(Chemical Equation Presented) Phosphine-free palladium nanoparticles were embedded in a fluorous organic-inorganic hybrid material 6b prepared by the sol-gel process. The use of Pdn·6b in the Heck coupling reaction under microwave irradiation has been investigated. Recycling studies have shown that the catalyst can be readily recovered and reused several times without significant loss of activity. Reactions and recovery of the solid-supported palladium catalyst system can be carried out in the presence of air, without any particular precaution. {\textcopyright} 2008 American Chemical Society.",

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AU - Alibés, Ramon

PY - 2008/12/1

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N2 - (Chemical Equation Presented) Phosphine-free palladium nanoparticles were embedded in a fluorous organic-inorganic hybrid material 6b prepared by the sol-gel process. The use of Pdn·6b in the Heck coupling reaction under microwave irradiation has been investigated. Recycling studies have shown that the catalyst can be readily recovered and reused several times without significant loss of activity. Reactions and recovery of the solid-supported palladium catalyst system can be carried out in the presence of air, without any particular precaution. © 2008 American Chemical Society.

AB - (Chemical Equation Presented) Phosphine-free palladium nanoparticles were embedded in a fluorous organic-inorganic hybrid material 6b prepared by the sol-gel process. The use of Pdn·6b in the Heck coupling reaction under microwave irradiation has been investigated. Recycling studies have shown that the catalyst can be readily recovered and reused several times without significant loss of activity. Reactions and recovery of the solid-supported palladium catalyst system can be carried out in the presence of air, without any particular precaution. © 2008 American Chemical Society.

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