Palladium nanoparticles obtained from palladium salts and tributylamine in molten tetrabutylammonium bromide: Their use for hydrogenolysis-free hydrogenation of olefins

Jean Le Bras, Deb Kumar Mukherjee, Sara González, Mar Tristany, Benjamin Ganchegui, Marcial Moreno-Mañas, Roser Pleixats, Françoise Hénin, Jacques Muzart

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57 Citations (Scopus)

Abstract

Carbon-carbon double bonds have been selectively hydrogenated at room temperature in the presence of benzyloxy groups using an atmospheric pressure of hydrogen, toluene or [bmim]PF6 as the solvent and palladium nanoparticles stabilized with tetrabutylammonium bromide. The system [bmim]PF6/palladium nanoparticles can be recycled without noticeable decrease of activity.
Original languageEnglish
Pages (from-to)1550-1553
JournalNew Journal of Chemistry
Volume28
Issue number12
DOIs
Publication statusPublished - 1 Dec 2004

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