Palladium nanoparticles obtained from palladium salts and tributylamine in molten tetrabutylammonium bromide: Their use for hydrogenolysis-free hydrogenation of olefins

Jean Le Bras; Deb Kumar Mukherjee; Sara González; Mar Tristany; Benjamin Ganchegui; Marcial Moreno-Mañas; Roser Pleixats; Françoise Hénin; Jacques Muzart

doi:10.1039/b409604e

Palladium nanoparticles obtained from palladium salts and tributylamine in molten tetrabutylammonium bromide: Their use for hydrogenolysis-free hydrogenation of olefins

Jean Le Bras, Deb Kumar Mukherjee, Sara González, Mar Tristany, Benjamin Ganchegui, Marcial Moreno-Mañas, Roser Pleixats, Françoise Hénin, Jacques Muzart

Department of Chemistry

Research output: Contribution to journal › Article › Research › peer-review

58 Citations (Scopus)

Abstract

Carbon-carbon double bonds have been selectively hydrogenated at room temperature in the presence of benzyloxy groups using an atmospheric pressure of hydrogen, toluene or [bmim]PF6 as the solvent and palladium nanoparticles stabilized with tetrabutylammonium bromide. The system [bmim]PF6/palladium nanoparticles can be recycled without noticeable decrease of activity.

Original language	English
Pages (from-to)	1550-1553
Journal	New Journal of Chemistry
Volume	28
Issue number	12
DOIs	https://doi.org/10.1039/b409604e
Publication status	Published - 1 Dec 2004

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Le Bras, J., Mukherjee, D. K., González, S., Tristany, M., Ganchegui, B., Moreno-Mañas, M., Pleixats, R., Hénin, F., & Muzart, J. (2004). Palladium nanoparticles obtained from palladium salts and tributylamine in molten tetrabutylammonium bromide: Their use for hydrogenolysis-free hydrogenation of olefins. New Journal of Chemistry, 28(12), 1550-1553. https://doi.org/10.1039/b409604e

Le Bras, Jean ; Mukherjee, Deb Kumar ; González, Sara ; Tristany, Mar ; Ganchegui, Benjamin ; Moreno-Mañas, Marcial ; Pleixats, Roser ; Hénin, Françoise ; Muzart, Jacques. / Palladium nanoparticles obtained from palladium salts and tributylamine in molten tetrabutylammonium bromide: Their use for hydrogenolysis-free hydrogenation of olefins. In: New Journal of Chemistry. 2004 ; Vol. 28, No. 12. pp. 1550-1553.

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abstract = "Carbon-carbon double bonds have been selectively hydrogenated at room temperature in the presence of benzyloxy groups using an atmospheric pressure of hydrogen, toluene or [bmim]PF6 as the solvent and palladium nanoparticles stabilized with tetrabutylammonium bromide. The system [bmim]PF6/palladium nanoparticles can be recycled without noticeable decrease of activity.",

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Le Bras, J, Mukherjee, DK, González, S, Tristany, M, Ganchegui, B, Moreno-Mañas, M, Pleixats, R, Hénin, F & Muzart, J 2004, 'Palladium nanoparticles obtained from palladium salts and tributylamine in molten tetrabutylammonium bromide: Their use for hydrogenolysis-free hydrogenation of olefins', New Journal of Chemistry, vol. 28, no. 12, pp. 1550-1553. https://doi.org/10.1039/b409604e

Palladium nanoparticles obtained from palladium salts and tributylamine in molten tetrabutylammonium bromide: Their use for hydrogenolysis-free hydrogenation of olefins. / Le Bras, Jean; Mukherjee, Deb Kumar; González, Sara; Tristany, Mar; Ganchegui, Benjamin; Moreno-Mañas, Marcial; Pleixats, Roser; Hénin, Françoise; Muzart, Jacques.

In: New Journal of Chemistry, Vol. 28, No. 12, 01.12.2004, p. 1550-1553.

Research output: Contribution to journal › Article › Research › peer-review

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AU - Le Bras, Jean

AU - Mukherjee, Deb Kumar

AU - González, Sara

AU - Tristany, Mar

AU - Ganchegui, Benjamin

AU - Moreno-Mañas, Marcial

AU - Pleixats, Roser

AU - Hénin, Françoise

AU - Muzart, Jacques

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AB - Carbon-carbon double bonds have been selectively hydrogenated at room temperature in the presence of benzyloxy groups using an atmospheric pressure of hydrogen, toluene or [bmim]PF6 as the solvent and palladium nanoparticles stabilized with tetrabutylammonium bromide. The system [bmim]PF6/palladium nanoparticles can be recycled without noticeable decrease of activity.

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DO - 10.1039/b409604e

M3 - Article

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SP - 1550

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ER -

Palladium nanoparticles obtained from palladium salts and tributylamine in molten tetrabutylammonium bromide: Their use for hydrogenolysis-free hydrogenation of olefins

Abstract

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