Palladium nanoparticles entrapped in heavily fluorinated compounds

Mar Tristany, James Courmarcel, Philippe Dieudonné, Marcial Moreno-Mañas, Roser Pleixats, Albert Rimola, Mariona Sodupe, Silvia Villarroya

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34 Citations (Scopus)

Abstract

Palladium nanoparticles formed by the reduction of palladium(II) chloride with methanol or 2-propanol are stabilized by entrapment in solid heavily fluorinated compounds, as suggested by powder X-ray diffraction. Some of the stabilizers are fluorohydrocarbons without a functional group. Calculations suggest that minor amounts of Pd(II) on the surface of the nanoparticles might be the origin of attractive interactions with the negative periphery of perfluorinated chains (CnF2n+1. The role of sodium acetate in the precipitation of nanoparticles is underlined. © 2006 American Chemical Society.
Original languageEnglish
Pages (from-to)716-722
JournalChemistry of Materials
Volume18
Issue number3
DOIs
Publication statusPublished - 7 Feb 2006

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    Tristany, M., Courmarcel, J., Dieudonné, P., Moreno-Mañas, M., Pleixats, R., Rimola, A., Sodupe, M., & Villarroya, S. (2006). Palladium nanoparticles entrapped in heavily fluorinated compounds. Chemistry of Materials, 18(3), 716-722. https://doi.org/10.1021/cm051967a