Abstract
Pd(PEt3)2(OTf)2, acting as an in situ source of Pd(PEt3)2, reacts with an alkyne and hydrogen via phosphine loss to form the detectable hydride-containing species Pd(PEt3)2(H)(CHPhCH2Ph), cis- and trans-Pd(PEt3)2(H)(CPh=CHPh), and Pd2(PEt3)3(H)(CHPhCH2Ph)2+, which map onto the reaction scheme predicted by density functional theory. Copyright © 2006 American Chemical Society.
Original language | English |
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Pages (from-to) | 9596-9597 |
Journal | Journal of the American Chemical Society |
Volume | 128 |
Issue number | 30 |
DOIs | |
Publication status | Published - 2 Aug 2006 |