Palladium catalyzed allylic C-alkylation of highly acidic and enolic heterocyclic substrates: tetronic acid and triacetic acid lactone

Marcial Moreno-Mañas; Maria Prat; Jordi Ribas; Albert Virgili

doi:10.1016/S0040-4039(00)80156-2

Palladium catalyzed allylic C-alkylation of highly acidic and enolic heterocyclic substrates: tetronic acid and triacetic acid lactone

Marcial Moreno-Mañas, Maria Prat, Jordi Ribas, Albert Virgili

Department of Chemistry

Research output: Contribution to journal › Article › Research › peer-review

29 Citations (Scopus)

Abstract

Tetronic acid (pKa 3.76) and triacetic acid lactone (pKa 4.94) have been alkylated at their active carbon atoms by means of thermodinamically controlled palladium catalyzed allylic alkylations. © 1988.

Original language	English
Pages (from-to)	581-584
Journal	Tetrahedron Letters
Volume	29
Issue number	5
DOIs	https://doi.org/10.1016/S0040-4039(00)80156-2
Publication status	Published - 1 Jan 1988

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@article{77e4cb63895649f5a9d6b45bbfa4dc48,

title = "Palladium catalyzed allylic C-alkylation of highly acidic and enolic heterocyclic substrates: tetronic acid and triacetic acid lactone",

abstract = "Tetronic acid (pKa 3.76) and triacetic acid lactone (pKa 4.94) have been alkylated at their active carbon atoms by means of thermodinamically controlled palladium catalyzed allylic alkylations. {\textcopyright} 1988.",

author = "Marcial Moreno-Ma{\~n}as and Maria Prat and Jordi Ribas and Albert Virgili",

year = "1988",

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T1 - Palladium catalyzed allylic C-alkylation of highly acidic and enolic heterocyclic substrates: tetronic acid and triacetic acid lactone

AU - Moreno-Mañas, Marcial

AU - Prat, Maria

AU - Ribas, Jordi

AU - Virgili, Albert

PY - 1988/1/1

Y1 - 1988/1/1

N2 - Tetronic acid (pKa 3.76) and triacetic acid lactone (pKa 4.94) have been alkylated at their active carbon atoms by means of thermodinamically controlled palladium catalyzed allylic alkylations. © 1988.

AB - Tetronic acid (pKa 3.76) and triacetic acid lactone (pKa 4.94) have been alkylated at their active carbon atoms by means of thermodinamically controlled palladium catalyzed allylic alkylations. © 1988.

UR - https://www.scopus.com/pages/publications/0000492007

U2 - 10.1016/S0040-4039(00)80156-2

DO - 10.1016/S0040-4039(00)80156-2

M3 - Article

SN - 0040-4039

VL - 29

SP - 581

EP - 584

JO - Tetrahedron Letters

JF - Tetrahedron Letters

IS - 5

ER -

Palladium catalyzed allylic C-alkylation of highly acidic and enolic heterocyclic substrates: tetronic acid and triacetic acid lactone

Abstract

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