Oxygen carriers based on electrochemically reduced trinitroarenes

Iluminada Gallardo; Gonzalo Guirado

doi:10.1039/b801419a

Oxygen carriers based on electrochemically reduced trinitroarenes

Iluminada Gallardo, Gonzalo Guirado

Department of Chemistry

Research output: Contribution to journal › Article › Research › peer-review

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Abstract

1,3,5-Trinitrobenzene, 2,4,6-trinitrotoluene and 1-methoxy-2,4,6- trinitrobenzene undergoes reversible dimerization, after electrochemical reduction of two units of corresponding anion radical. The π-dimer formed captures molecular oxygen (O2) leading to a σ o-oH-adduct, in an atmosphere of oxygen or even air. The σo-oH-adduct is able to reversibly bind and remove dioxygen after an external redox stimulus. © the Owner Societies.

Original language	English
Pages (from-to)	4456-4462
Journal	Physical Chemistry Chemical Physics
Volume	10
Issue number	30
DOIs	https://doi.org/10.1039/b801419a
Publication status	Published - 30 Jul 2008

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title = "Oxygen carriers based on electrochemically reduced trinitroarenes",

abstract = "1,3,5-Trinitrobenzene, 2,4,6-trinitrotoluene and 1-methoxy-2,4,6- trinitrobenzene undergoes reversible dimerization, after electrochemical reduction of two units of corresponding anion radical. The π-dimer formed captures molecular oxygen (O2) leading to a σ o-oH-adduct, in an atmosphere of oxygen or even air. The σo-oH-adduct is able to reversibly bind and remove dioxygen after an external redox stimulus. {\textcopyright} the Owner Societies.",

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AU - Guirado, Gonzalo

PY - 2008/7/30

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N2 - 1,3,5-Trinitrobenzene, 2,4,6-trinitrotoluene and 1-methoxy-2,4,6- trinitrobenzene undergoes reversible dimerization, after electrochemical reduction of two units of corresponding anion radical. The π-dimer formed captures molecular oxygen (O2) leading to a σ o-oH-adduct, in an atmosphere of oxygen or even air. The σo-oH-adduct is able to reversibly bind and remove dioxygen after an external redox stimulus. © the Owner Societies.

AB - 1,3,5-Trinitrobenzene, 2,4,6-trinitrotoluene and 1-methoxy-2,4,6- trinitrobenzene undergoes reversible dimerization, after electrochemical reduction of two units of corresponding anion radical. The π-dimer formed captures molecular oxygen (O2) leading to a σ o-oH-adduct, in an atmosphere of oxygen or even air. The σo-oH-adduct is able to reversibly bind and remove dioxygen after an external redox stimulus. © the Owner Societies.

U2 - 10.1039/b801419a

DO - 10.1039/b801419a

M3 - Article

VL - 10

SP - 4456

EP - 4462

IS - 30

ER -

Oxygen carriers based on electrochemically reduced trinitroarenes

Abstract

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