O2 chemistry of dicopper complexes with alkyltriamine ligands. Comparing synergistic effects on O2 binding

Anna Company; Diana Lamata; Albert Poater; Miquel Solà; Elena V. Rybak-Akimova; Lawrence Que; Xavier Fontrodona; Teodor Parella; Antoni Llobet; Miquel Costas

doi:10.1021/ic0602446

O₂ chemistry of dicopper complexes with alkyltriamine ligands. Comparing synergistic effects on O₂ binding

Anna Company, Diana Lamata, Albert Poater, Miquel Solà, Elena V. Rybak-Akimova, Lawrence Que, Xavier Fontrodona, Teodor Parella, Antoni Llobet, Miquel Costas

Department of Chemistry

Research output: Contribution to journal › Article › Research › peer-review

22 Citations (Scopus)

Abstract

Two dicopper(I) complexes containing tertiary N-methylated hexaaza ligands which impose different steric constraints to the Cu ions have been synthesized, and their reactivity toward O2 has been compared with a mononuclear related system, highlighting the importance of cooperative effects between the metal centers in O2 activation. © 2006 American Chemical Society.

Original language	English
Pages (from-to)	5239-5241
Journal	Inorganic Chemistry
Volume	45
Issue number	14
DOIs	https://doi.org/10.1021/ic0602446
Publication status	Published - 10 Jul 2006

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10.1021/ic0602446

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@article{09280e0be9ce4636a295eb49685f7e48,

title = "O2 chemistry of dicopper complexes with alkyltriamine ligands. Comparing synergistic effects on O2 binding",

abstract = "Two dicopper(I) complexes containing tertiary N-methylated hexaaza ligands which impose different steric constraints to the Cu ions have been synthesized, and their reactivity toward O2 has been compared with a mononuclear related system, highlighting the importance of cooperative effects between the metal centers in O2 activation. {\textcopyright} 2006 American Chemical Society.",

author = "Anna Company and Diana Lamata and Albert Poater and Miquel Sol{\`a} and Rybak-Akimova, {Elena V.} and Lawrence Que and Xavier Fontrodona and Teodor Parella and Antoni Llobet and Miquel Costas",

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doi = "10.1021/ic0602446",

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T1 - O2 chemistry of dicopper complexes with alkyltriamine ligands. Comparing synergistic effects on O2 binding

AU - Company, Anna

AU - Lamata, Diana

AU - Poater, Albert

AU - Solà, Miquel

AU - Rybak-Akimova, Elena V.

AU - Que, Lawrence

AU - Fontrodona, Xavier

AU - Parella, Teodor

AU - Llobet, Antoni

AU - Costas, Miquel

PY - 2006/7/10

Y1 - 2006/7/10

N2 - Two dicopper(I) complexes containing tertiary N-methylated hexaaza ligands which impose different steric constraints to the Cu ions have been synthesized, and their reactivity toward O2 has been compared with a mononuclear related system, highlighting the importance of cooperative effects between the metal centers in O2 activation. © 2006 American Chemical Society.

AB - Two dicopper(I) complexes containing tertiary N-methylated hexaaza ligands which impose different steric constraints to the Cu ions have been synthesized, and their reactivity toward O2 has been compared with a mononuclear related system, highlighting the importance of cooperative effects between the metal centers in O2 activation. © 2006 American Chemical Society.

U2 - 10.1021/ic0602446

DO - 10.1021/ic0602446

M3 - Article

VL - 45

SP - 5239

EP - 5241

IS - 14

ER -

O2 chemistry of dicopper complexes with alkyltriamine ligands. Comparing synergistic effects on O2 binding

Abstract

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O₂ chemistry of dicopper complexes with alkyltriamine ligands. Comparing synergistic effects on O₂ binding