O2 chemistry of dicopper complexes with alkyltriamine ligands. Comparing synergistic effects on O2 binding

Anna Company, Diana Lamata, Albert Poater, Miquel Solà, Elena V. Rybak-Akimova, Lawrence Que, Xavier Fontrodona, Teodor Parella, Antoni Llobet, Miquel Costas

Research output: Contribution to journalArticleResearchpeer-review

17 Citations (Scopus)

Abstract

Two dicopper(I) complexes containing tertiary N-methylated hexaaza ligands which impose different steric constraints to the Cu ions have been synthesized, and their reactivity toward O2 has been compared with a mononuclear related system, highlighting the importance of cooperative effects between the metal centers in O2 activation. © 2006 American Chemical Society.
Original languageEnglish
Pages (from-to)5239-5241
JournalInorganic Chemistry
Volume45
Issue number14
DOIs
Publication statusPublished - 10 Jul 2006

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