Ortho-CH Activation of Aromatic Ketones, Partially Fluorinated Aromatic Ketones, and Aromatic Imines by a Trihydride-Stannyl-Osmium(IV) Complex

Miguel A. Esteruelas, Agustí Lledós, Montserrat Oliván, Enrique Oñate, María A. Tajada, Gregori Ujaque

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56 Citations (Scopus)

Abstract

Ortho-CH activation of aromatic ketones, partially fluorinated aromatic ketones, and aromatic imines was investigated using a trihydride-stannyl-osmium(IV) complex. The reaction pathway for the formation of intermediate was evaluated by density functional theory (DFT). The results indicate that the formed products are classical dihydrides and that there is no interactions between the tin atom and any of the hydride ligands.
Original languageEnglish
Pages (from-to)3753-3765
JournalOrganometallics
Volume22
Issue number18
DOIs
Publication statusPublished - 1 Sep 2003

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