Ortho-CH Activation of Aromatic Ketones, Partially Fluorinated Aromatic Ketones, and Aromatic Imines by a Trihydride-Stannyl-Osmium(IV) Complex

Miguel A. Esteruelas; Agustí Lledós; Montserrat Oliván; Enrique Oñate; María A. Tajada; Gregori Ujaque

doi:10.1021/om030229y

Ortho-CH Activation of Aromatic Ketones, Partially Fluorinated Aromatic Ketones, and Aromatic Imines by a Trihydride-Stannyl-Osmium(IV) Complex

Miguel A. Esteruelas, Agustí Lledós, Montserrat Oliván, Enrique Oñate, María A. Tajada, Gregori Ujaque

Department of Chemistry

Research output: Contribution to journal › Article › Research › peer-review

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Abstract

Ortho-CH activation of aromatic ketones, partially fluorinated aromatic ketones, and aromatic imines was investigated using a trihydride-stannyl-osmium(IV) complex. The reaction pathway for the formation of intermediate was evaluated by density functional theory (DFT). The results indicate that the formed products are classical dihydrides and that there is no interactions between the tin atom and any of the hydride ligands.

Original language	English
Pages (from-to)	3753-3765
Journal	Organometallics
Volume	22
Issue number	18
DOIs	https://doi.org/10.1021/om030229y
Publication status	Published - 1 Sept 2003

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title = "Ortho-CH Activation of Aromatic Ketones, Partially Fluorinated Aromatic Ketones, and Aromatic Imines by a Trihydride-Stannyl-Osmium(IV) Complex",

abstract = "Ortho-CH activation of aromatic ketones, partially fluorinated aromatic ketones, and aromatic imines was investigated using a trihydride-stannyl-osmium(IV) complex. The reaction pathway for the formation of intermediate was evaluated by density functional theory (DFT). The results indicate that the formed products are classical dihydrides and that there is no interactions between the tin atom and any of the hydride ligands.",

author = "Esteruelas, {Miguel A.} and Agust{\'i} Lled{\'o}s and Montserrat Oliv{\'a}n and Enrique O{\~n}ate and Tajada, {Mar{\'i}a A.} and Gregori Ujaque",

year = "2003",

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T1 - Ortho-CH Activation of Aromatic Ketones, Partially Fluorinated Aromatic Ketones, and Aromatic Imines by a Trihydride-Stannyl-Osmium(IV) Complex

AU - Esteruelas, Miguel A.

AU - Lledós, Agustí

AU - Oliván, Montserrat

AU - Oñate, Enrique

AU - Tajada, María A.

AU - Ujaque, Gregori

PY - 2003/9/1

Y1 - 2003/9/1

N2 - Ortho-CH activation of aromatic ketones, partially fluorinated aromatic ketones, and aromatic imines was investigated using a trihydride-stannyl-osmium(IV) complex. The reaction pathway for the formation of intermediate was evaluated by density functional theory (DFT). The results indicate that the formed products are classical dihydrides and that there is no interactions between the tin atom and any of the hydride ligands.

AB - Ortho-CH activation of aromatic ketones, partially fluorinated aromatic ketones, and aromatic imines was investigated using a trihydride-stannyl-osmium(IV) complex. The reaction pathway for the formation of intermediate was evaluated by density functional theory (DFT). The results indicate that the formed products are classical dihydrides and that there is no interactions between the tin atom and any of the hydride ligands.

U2 - 10.1021/om030229y

DO - 10.1021/om030229y

M3 - Article

SN - 0276-7333

VL - 22

SP - 3753

EP - 3765

JO - Organometallics

JF - Organometallics

IS - 18

ER -

Ortho-CH Activation of Aromatic Ketones, Partially Fluorinated Aromatic Ketones, and Aromatic Imines by a Trihydride-Stannyl-Osmium(IV) Complex

Abstract

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