Origin of enantioselectivity in asymmetric Pauson-Khand reactions catalyzed by [(BINAP)Co<inf>2</inf>(CO)<inf>6</inf>]

Torstein Fjermestad, Miquel A. Perics, Feliu Maseras

Research output: Contribution to journalArticleResearchpeer-review

10 Citations (Scopus)

Abstract

The selectivity in the Pauson-Khand intramolecular cyclization of prochiral enynes catalyzed by [(BINAP)Co2(CO)6] is controlled by enyne-phenyl and carbonyl-phenyl steric repulsions. © 2010 Elsevier B.V. All rights reserved.
Original languageEnglish
Pages (from-to)127-132
JournalJournal of Molecular Catalysis A: Chemical
Volume324
Issue number1-2
DOIs
Publication statusPublished - 30 Mar 2010

Keywords

  • Enantioselectivity
  • Pauson-Khand reaction
  • QM/MM methods

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