Organic-inorganic hybrid silica material derived from a monosilylated Grubbs-Hoveyda ruthenium carbene as a recyclable metathesis catalyst

Guadalupe Borja; Roser Pleixats; Ramón Alibés; Xavier Cattoën; Michel Wong Chi Man

doi:https://doi.org/10.3390/molecules15085756

Organic-inorganic hybrid silica material derived from a monosilylated Grubbs-Hoveyda ruthenium carbene as a recyclable metathesis catalyst

Guadalupe Borja, Roser Pleixats, Ramón Alibés, Xavier Cattoën, Michel Wong Chi Man

Department of Chemistry

Research output: Contribution to journal › Article › Research › peer-review

13 Citations (Scopus)

Abstract

The synthesis of a monosilylated Grubbs-Hoveyda ruthenium alkylidene complex is described, as well as the preparation and characterization of the corresponding material by sol-gel cogelification with tetraethoxysilane (TEOS) and the assay of this recyclable supported catalyst in ring-closing diene and enyne metathesis reactions under thermal and microwave conditions. © 2010 by the authors.

Original language	English
Pages (from-to)	5756-5767
Journal	Molecules
Volume	15
Issue number	8
DOIs	https://doi.org/10.3390/molecules15085756
Publication status	Published - 1 Aug 2010

Keywords

Catalyst immobilization
Organic-inorganic hybrid material
Ring-closing metathesis
Ruthenium alkylidene
Sol-gel process

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https://doi.org/10.3390/molecules15085756

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title = "Organic-inorganic hybrid silica material derived from a monosilylated Grubbs-Hoveyda ruthenium carbene as a recyclable metathesis catalyst",

abstract = "The synthesis of a monosilylated Grubbs-Hoveyda ruthenium alkylidene complex is described, as well as the preparation and characterization of the corresponding material by sol-gel cogelification with tetraethoxysilane (TEOS) and the assay of this recyclable supported catalyst in ring-closing diene and enyne metathesis reactions under thermal and microwave conditions. {\textcopyright} 2010 by the authors.",

keywords = "Catalyst immobilization, Organic-inorganic hybrid material, Ring-closing metathesis, Ruthenium alkylidene, Sol-gel process",

author = "Guadalupe Borja and Roser Pleixats and Ram{\'o}n Alib{\'e}s and Xavier Catto{\"e}n and {Chi Man}, {Michel Wong}",

year = "2010",

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doi = "https://doi.org/10.3390/molecules15085756",

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TY - JOUR

T1 - Organic-inorganic hybrid silica material derived from a monosilylated Grubbs-Hoveyda ruthenium carbene as a recyclable metathesis catalyst

AU - Borja, Guadalupe

AU - Pleixats, Roser

AU - Alibés, Ramón

AU - Cattoën, Xavier

AU - Chi Man, Michel Wong

PY - 2010/8/1

Y1 - 2010/8/1

N2 - The synthesis of a monosilylated Grubbs-Hoveyda ruthenium alkylidene complex is described, as well as the preparation and characterization of the corresponding material by sol-gel cogelification with tetraethoxysilane (TEOS) and the assay of this recyclable supported catalyst in ring-closing diene and enyne metathesis reactions under thermal and microwave conditions. © 2010 by the authors.

AB - The synthesis of a monosilylated Grubbs-Hoveyda ruthenium alkylidene complex is described, as well as the preparation and characterization of the corresponding material by sol-gel cogelification with tetraethoxysilane (TEOS) and the assay of this recyclable supported catalyst in ring-closing diene and enyne metathesis reactions under thermal and microwave conditions. © 2010 by the authors.

KW - Catalyst immobilization

KW - Organic-inorganic hybrid material

KW - Ring-closing metathesis

KW - Ruthenium alkylidene

KW - Sol-gel process

U2 - https://doi.org/10.3390/molecules15085756

DO - https://doi.org/10.3390/molecules15085756

M3 - Article

SN - 1420-3049

VL - 15

SP - 5756

EP - 5767

JO - Molecules

JF - Molecules

IS - 8

ER -

Organic-inorganic hybrid silica material derived from a monosilylated Grubbs-Hoveyda ruthenium carbene as a recyclable metathesis catalyst

Abstract

Keywords

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