Organic-inorganic hybrid materials containing 15-membered azamacrocyclic triolefinic palladium(0) complexes. Preparation and activity as recoverable catalysts in Suzuki cross-couplings

Belén Blanco; Marcial Moreno-Mañas; Roser Pleixats; Ahmad Mehdi; Catherine Reyé

doi:10.1016/j.molcata.2007.01.026

Organic-inorganic hybrid materials containing 15-membered azamacrocyclic triolefinic palladium(0) complexes. Preparation and activity as recoverable catalysts in Suzuki cross-couplings

Belén Blanco, Marcial Moreno-Mañas, Roser Pleixats, Ahmad Mehdi, Catherine Reyé

Department of Chemistry

Research output: Contribution to journal › Article › Research › peer-review

21 Citations (Scopus)

Abstract

The synthesis of a palladium complex and a monosilylated monomer derived from 15-membered azatriolefinic macrocycle are described as well as the preparation of the corresponding hybrid organic-inorganic materials, containing a macrocyclic palladium(0) complex covalently anchored to the silica matrix. The materials were obtained by sol-gel process using different routes: post-synthesis treatment on a mesostructured silica, cogelification of a monosilylated precursor and tetraethylorthosilicate. The activity of the different materials as recoverable catalysts in Suzuki cross-couplings is reported and commented. © 2007 Elsevier B.V. All rights reserved.

Original language	English
Pages (from-to)	204-213
Journal	Journal of Molecular Catalysis A: Chemical
Volume	269
Issue number	1-2
DOIs	https://doi.org/10.1016/j.molcata.2007.01.026
Publication status	Published - 18 May 2007

Keywords

Cross-coupling
Macrocycles
Palladium supported catalyst
Recyclable catalyst
Sol-gel processes

Access to Document

10.1016/j.molcata.2007.01.026

Cite this

Blanco, B., Moreno-Mañas, M., Pleixats, R., Mehdi, A., & Reyé, C. (2007). Organic-inorganic hybrid materials containing 15-membered azamacrocyclic triolefinic palladium(0) complexes. Preparation and activity as recoverable catalysts in Suzuki cross-couplings. Journal of Molecular Catalysis A: Chemical, 269(1-2), 204-213. https://doi.org/10.1016/j.molcata.2007.01.026

@article{95a3f5502cae477ebf715945308ae920,

title = "Organic-inorganic hybrid materials containing 15-membered azamacrocyclic triolefinic palladium(0) complexes. Preparation and activity as recoverable catalysts in Suzuki cross-couplings",

abstract = "The synthesis of a palladium complex and a monosilylated monomer derived from 15-membered azatriolefinic macrocycle are described as well as the preparation of the corresponding hybrid organic-inorganic materials, containing a macrocyclic palladium(0) complex covalently anchored to the silica matrix. The materials were obtained by sol-gel process using different routes: post-synthesis treatment on a mesostructured silica, cogelification of a monosilylated precursor and tetraethylorthosilicate. The activity of the different materials as recoverable catalysts in Suzuki cross-couplings is reported and commented. {\textcopyright} 2007 Elsevier B.V. All rights reserved.",

keywords = "Cross-coupling, Macrocycles, Palladium supported catalyst, Recyclable catalyst, Sol-gel processes",

author = "Bel{\'e}n Blanco and Marcial Moreno-Ma{\~n}as and Roser Pleixats and Ahmad Mehdi and Catherine Rey{\'e}",

year = "2007",

month = may,

day = "18",

doi = "10.1016/j.molcata.2007.01.026",

language = "English",

volume = "269",

pages = "204--213",

journal = "Journal of Molecular Catalysis A: Chemical",

issn = "1381-1169",

publisher = "Elsevier",

number = "1-2",

}

Blanco, B, Moreno-Mañas, M, Pleixats, R, Mehdi, A & Reyé, C 2007, 'Organic-inorganic hybrid materials containing 15-membered azamacrocyclic triolefinic palladium(0) complexes. Preparation and activity as recoverable catalysts in Suzuki cross-couplings', Journal of Molecular Catalysis A: Chemical, vol. 269, no. 1-2, pp. 204-213. https://doi.org/10.1016/j.molcata.2007.01.026

Organic-inorganic hybrid materials containing 15-membered azamacrocyclic triolefinic palladium(0) complexes. Preparation and activity as recoverable catalysts in Suzuki cross-couplings. / Blanco, Belén; Moreno-Mañas, Marcial; Pleixats, Roser et al.
In: Journal of Molecular Catalysis A: Chemical, Vol. 269, No. 1-2, 18.05.2007, p. 204-213.

Research output: Contribution to journal › Article › Research › peer-review

TY - JOUR

T1 - Organic-inorganic hybrid materials containing 15-membered azamacrocyclic triolefinic palladium(0) complexes. Preparation and activity as recoverable catalysts in Suzuki cross-couplings

AU - Blanco, Belén

AU - Moreno-Mañas, Marcial

AU - Pleixats, Roser

AU - Mehdi, Ahmad

AU - Reyé, Catherine

PY - 2007/5/18

Y1 - 2007/5/18

N2 - The synthesis of a palladium complex and a monosilylated monomer derived from 15-membered azatriolefinic macrocycle are described as well as the preparation of the corresponding hybrid organic-inorganic materials, containing a macrocyclic palladium(0) complex covalently anchored to the silica matrix. The materials were obtained by sol-gel process using different routes: post-synthesis treatment on a mesostructured silica, cogelification of a monosilylated precursor and tetraethylorthosilicate. The activity of the different materials as recoverable catalysts in Suzuki cross-couplings is reported and commented. © 2007 Elsevier B.V. All rights reserved.

AB - The synthesis of a palladium complex and a monosilylated monomer derived from 15-membered azatriolefinic macrocycle are described as well as the preparation of the corresponding hybrid organic-inorganic materials, containing a macrocyclic palladium(0) complex covalently anchored to the silica matrix. The materials were obtained by sol-gel process using different routes: post-synthesis treatment on a mesostructured silica, cogelification of a monosilylated precursor and tetraethylorthosilicate. The activity of the different materials as recoverable catalysts in Suzuki cross-couplings is reported and commented. © 2007 Elsevier B.V. All rights reserved.

KW - Cross-coupling

KW - Macrocycles

KW - Palladium supported catalyst

KW - Recyclable catalyst

KW - Sol-gel processes

U2 - 10.1016/j.molcata.2007.01.026

DO - 10.1016/j.molcata.2007.01.026

M3 - Article

SN - 1381-1169

VL - 269

SP - 204

EP - 213

JO - Journal of Molecular Catalysis A: Chemical

JF - Journal of Molecular Catalysis A: Chemical

IS - 1-2

ER -

Organic-inorganic hybrid materials containing 15-membered azamacrocyclic triolefinic palladium(0) complexes. Preparation and activity as recoverable catalysts in Suzuki cross-couplings

Abstract

Keywords

Access to Document

Fingerprint

Cite this