One step synthesis of a new asymmetric water-soluble phosphine

Mireia Condom, Joan Suades

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3 Citations (Scopus)

Abstract

The new asymmetric water-soluble phosphine (S)-(-)-(3-diphenylphosphino-2- hydroxypropyl)trimethylammonium chloride was synthesised from the accessible (S)-(-)-(3-chloro-2-hydroxypropyl)trimethylammonium chloride by means of a one pot reaction between this ionic compound and sodium diphenylphosphide in liquid ammonia. The palladium complex (L)PdCl3 (L = (S)-(-)-(3- diphenylphosphino-2-hydroxypropyl)trimethylammonium) was prepared by reaction between this ligand and PdCl2(PhCN)2 and was characterised by spectroscopic methods. © 2005 Elsevier B.V. All rights reserved.
Original languageEnglish
Pages (from-to)355-357
JournalInorganic Chemistry Communications
Volume8
Issue number4
DOIs
Publication statusPublished - 1 Jan 2005

Keywords

  • Asymmetric
  • Pd(II) complex
  • Phosphine
  • Water-soluble

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    Condom, M., & Suades, J. (2005). One step synthesis of a new asymmetric water-soluble phosphine. Inorganic Chemistry Communications, 8(4), 355-357. https://doi.org/10.1016/j.inoche.2005.01.015