One step synthesis of a new asymmetric water-soluble phosphine

Mireia Condom; Joan Suades

doi:10.1016/j.inoche.2005.01.015

One step synthesis of a new asymmetric water-soluble phosphine

Mireia Condom, Joan Suades

Department of Chemistry

Research output: Contribution to journal › Article › Research › peer-review

3 Citations (Scopus)

Abstract

The new asymmetric water-soluble phosphine (S)-(-)-(3-diphenylphosphino-2- hydroxypropyl)trimethylammonium chloride was synthesised from the accessible (S)-(-)-(3-chloro-2-hydroxypropyl)trimethylammonium chloride by means of a one pot reaction between this ionic compound and sodium diphenylphosphide in liquid ammonia. The palladium complex (L)PdCl3 (L = (S)-(-)-(3- diphenylphosphino-2-hydroxypropyl)trimethylammonium) was prepared by reaction between this ligand and PdCl2(PhCN)2 and was characterised by spectroscopic methods. © 2005 Elsevier B.V. All rights reserved.

Original language	English
Pages (from-to)	355-357
Journal	Inorganic Chemistry Communications
Volume	8
Issue number	4
DOIs	https://doi.org/10.1016/j.inoche.2005.01.015
Publication status	Published - 1 Jan 2005

Keywords

Asymmetric
Pd(II) complex
Phosphine
Water-soluble

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10.1016/j.inoche.2005.01.015

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title = "One step synthesis of a new asymmetric water-soluble phosphine",

abstract = "The new asymmetric water-soluble phosphine (S)-(-)-(3-diphenylphosphino-2- hydroxypropyl)trimethylammonium chloride was synthesised from the accessible (S)-(-)-(3-chloro-2-hydroxypropyl)trimethylammonium chloride by means of a one pot reaction between this ionic compound and sodium diphenylphosphide in liquid ammonia. The palladium complex (L)PdCl3 (L = (S)-(-)-(3- diphenylphosphino-2-hydroxypropyl)trimethylammonium) was prepared by reaction between this ligand and PdCl2(PhCN)2 and was characterised by spectroscopic methods. {\textcopyright} 2005 Elsevier B.V. All rights reserved.",

keywords = "Asymmetric, Pd(II) complex, Phosphine, Water-soluble",

author = "Mireia Condom and Joan Suades",

year = "2005",

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doi = "10.1016/j.inoche.2005.01.015",

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T1 - One step synthesis of a new asymmetric water-soluble phosphine

AU - Condom, Mireia

AU - Suades, Joan

PY - 2005/1/1

Y1 - 2005/1/1

N2 - The new asymmetric water-soluble phosphine (S)-(-)-(3-diphenylphosphino-2- hydroxypropyl)trimethylammonium chloride was synthesised from the accessible (S)-(-)-(3-chloro-2-hydroxypropyl)trimethylammonium chloride by means of a one pot reaction between this ionic compound and sodium diphenylphosphide in liquid ammonia. The palladium complex (L)PdCl3 (L = (S)-(-)-(3- diphenylphosphino-2-hydroxypropyl)trimethylammonium) was prepared by reaction between this ligand and PdCl2(PhCN)2 and was characterised by spectroscopic methods. © 2005 Elsevier B.V. All rights reserved.

AB - The new asymmetric water-soluble phosphine (S)-(-)-(3-diphenylphosphino-2- hydroxypropyl)trimethylammonium chloride was synthesised from the accessible (S)-(-)-(3-chloro-2-hydroxypropyl)trimethylammonium chloride by means of a one pot reaction between this ionic compound and sodium diphenylphosphide in liquid ammonia. The palladium complex (L)PdCl3 (L = (S)-(-)-(3- diphenylphosphino-2-hydroxypropyl)trimethylammonium) was prepared by reaction between this ligand and PdCl2(PhCN)2 and was characterised by spectroscopic methods. © 2005 Elsevier B.V. All rights reserved.

KW - Asymmetric

KW - Pd(II) complex

KW - Phosphine

KW - Water-soluble

U2 - 10.1016/j.inoche.2005.01.015

DO - 10.1016/j.inoche.2005.01.015

M3 - Article

SN - 1387-7003

VL - 8

SP - 355

EP - 357

JO - Inorganic Chemistry Communication

JF - Inorganic Chemistry Communication

IS - 4

ER -

One step synthesis of a new asymmetric water-soluble phosphine

Abstract

Keywords

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