On the mechanism of Diels-Alder reactions catalyzed by Lewis acids

V. Branchadell; A. Oliva; J. Bertran

doi:10.1016/0009-2614(85)80941-6

On the mechanism of Diels-Alder reactions catalyzed by Lewis acids

V. Branchadell, A. Oliva, J. Bertran

Department of Chemistry

Research output: Contribution to journal › Article › Research › peer-review

17 Citations (Scopus)

Abstract

The effect of Lewis acid catalysts on the mechanism of Diels-Alder reactions is studied using the MINDO/3 method. It is found that they tend to increase the two-step character of the process through a more important participation of the charge-transfer configuration. © 1985.

Original language	English
Pages (from-to)	197-201
Journal	Chemical Physics Letters
Volume	113
Issue number	2
DOIs	https://doi.org/10.1016/0009-2614(85)80941-6
Publication status	Published - 11 Jan 1985

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title = "On the mechanism of Diels-Alder reactions catalyzed by Lewis acids",

abstract = "The effect of Lewis acid catalysts on the mechanism of Diels-Alder reactions is studied using the MINDO/3 method. It is found that they tend to increase the two-step character of the process through a more important participation of the charge-transfer configuration. {\textcopyright} 1985.",

author = "V. Branchadell and A. Oliva and J. Bertran",

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AU - Oliva, A.

AU - Bertran, J.

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N2 - The effect of Lewis acid catalysts on the mechanism of Diels-Alder reactions is studied using the MINDO/3 method. It is found that they tend to increase the two-step character of the process through a more important participation of the charge-transfer configuration. © 1985.

AB - The effect of Lewis acid catalysts on the mechanism of Diels-Alder reactions is studied using the MINDO/3 method. It is found that they tend to increase the two-step character of the process through a more important participation of the charge-transfer configuration. © 1985.

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DO - 10.1016/0009-2614(85)80941-6

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SP - 197

EP - 201

JO - Chemical Physics Letters

JF - Chemical Physics Letters

SN - 0009-2614

IS - 2

ER -

On the mechanism of Diels-Alder reactions catalyzed by Lewis acids

Abstract

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