Novel stacking in a binuclear iridium carbonyl imidazoledicarboxylate

Gemma Net; J. Carlos Bayón; William M. Butler; Paul Rasmussen

doi:10.1039/C39890001022

Novel stacking in a binuclear iridium carbonyl imidazoledicarboxylate

Gemma Net, J. Carlos Bayón, William M. Butler, Paul Rasmussen

Department of Chemistry

Research output: Contribution to journal › Article › Research › peer-review

34 Citations (Scopus)

Abstract

The crystal structure of [Bu<inf>4</inf>N][lr<inf>2</inf>(mdcbi)(CO) <inf>4</inf>]·CH<inf>2</inf>Cl<inf>2</inf> (H<inf>3</inf>mdcbi = 2-methylimidazole-4,5-dicarboxylic acid) shows a new type of stacking in which the two iridium atoms of the binuclear complex are both involved in extended metal-metal chains at nearly identical distances.

Original language	English
Pages (from-to)	1022-1023
Journal	Journal of the Chemical Society, Chemical Communications
Issue number	15
DOIs	https://doi.org/10.1039/C39890001022
Publication status	Published - 1 Jan 1989

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title = "Novel stacking in a binuclear iridium carbonyl imidazoledicarboxylate",

abstract = "The crystal structure of [Bu4N][lr2(mdcbi)(CO) 4]·CH2Cl2 (H3mdcbi = 2-methylimidazole-4,5-dicarboxylic acid) shows a new type of stacking in which the two iridium atoms of the binuclear complex are both involved in extended metal-metal chains at nearly identical distances.",

author = "Gemma Net and Bay{\'o}n, {J. Carlos} and Butler, {William M.} and Paul Rasmussen",

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AU - Net, Gemma

AU - Bayón, J. Carlos

AU - Butler, William M.

AU - Rasmussen, Paul

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Y1 - 1989/1/1

N2 - The crystal structure of [Bu4N][lr2(mdcbi)(CO) 4]·CH2Cl2 (H3mdcbi = 2-methylimidazole-4,5-dicarboxylic acid) shows a new type of stacking in which the two iridium atoms of the binuclear complex are both involved in extended metal-metal chains at nearly identical distances.

AB - The crystal structure of [Bu4N][lr2(mdcbi)(CO) 4]·CH2Cl2 (H3mdcbi = 2-methylimidazole-4,5-dicarboxylic acid) shows a new type of stacking in which the two iridium atoms of the binuclear complex are both involved in extended metal-metal chains at nearly identical distances.

U2 - 10.1039/C39890001022

DO - 10.1039/C39890001022

M3 - Article

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