Nitrogen-nitrogen bond cleavage catalyzed by ruthenium complexes

Sandra Martínez, Elisenda Trepat, Marcial Moreno-Mañas, Rosa María Sebastián, Adelina Vallribera, Ignasi Mata, Elies Molins

Research output: Contribution to journalArticleResearchpeer-review

3 Citations (Scopus)

Abstract

Several ruthenium complexes have been tested as catalysts for the cleavage of nitrogen-nitrogen bonds of mono, di and trisubstituted hydrazine derivatives. Better results were obtained using Ru3(CO)12 as catalyst in this type of reactions. Addition of hydrogen sources, such as isopropanol or sodium hydride, to the reaction mixtures has been studied in order to improve the cleavage process. ©ARKAT USA, Inc.
Original languageEnglish
Pages (from-to)170-181
JournalArkivoc
Volume2007
Issue number4
Publication statusPublished - 1 Jan 2007

Keywords

  • Azodicarboxylate
  • Hydrazine
  • Nitrogen-nitrogen bond cleavage
  • Ruthenium catalyst

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