A new synthetic procedure is described to prepare acidopentacyano-cobaltate (III) complexes: [Co(CN)5X]3− (X = Cl,Br,I,NO2). Salts of [Co(CN)5N3]3− are treated with KNO2 in acid medium in the presence of the coordinating anion X. The compounds were characterized by spectrophotometric and analytical techniques. © 1986, Taylor & Francis Group, LLC. All rights reserved.
|Journal||Synthesis and Reactivity in Inorganic and Metal-Organic Chemistry|
|Publication status||Published - 1 Jan 1986|