New synthesis of acidopentacyanocobaltate(III) complexes

T. Flor, J. Casabó

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A new synthetic procedure is described to prepare acidopentacyano-cobaltate (III) complexes: [Co(CN)5X]3− (X = Cl,Br,I,NO2). Salts of [Co(CN)5N3]3− are treated with KNO2 in acid medium in the presence of the coordinating anion X. The compounds were characterized by spectrophotometric and analytical techniques. © 1986, Taylor & Francis Group, LLC. All rights reserved.
Original languageEnglish
Pages (from-to)795-800
JournalSynthesis and Reactivity in Inorganic and Metal-Organic Chemistry
Issue number6
Publication statusPublished - 1 Jan 1986


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