New heterotrinuclear complexes containing copper(II) and a group IV metal

Khwaja Salahuddin Siddiqi, Fathi Mohd Amin Mohd Aqra, Shakeel Ahmad Shah, Saiyid Aftab Ahmad Zaidi, Jaume Casabo, Francesc Teixidor

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2 Citations (Scopus)

Abstract

Heterotrinuclear complexes of the type [Cu2(TETA)2Cl4M] (M = Si, Ge, Sn, Ti and Zr; TETA = triethylene tetramine) have been prepared by direct reaction of [Cu[TETA)]Cl2 with MCl4 in a 2:1 ratio in MeOH. The compounds have been characterized by elemental analyses, e.s.r., electronic and i.r. spectra, magnetic susceptibility and conductivity measurements. The results indicate that [Cu(TETA)]Cl2 is square planar and ionic, while its heterotrinuclear complexes, [Cu2(TETA)2Cl4M], are covalent with an octahedral environment around the copper(II) ion. © 1994 Chapman & Hall.
Original languageEnglish
Pages (from-to)350-352
JournalTransit. Met. Chem. (Weinh.)
Volume19
Issue number3
DOIs
Publication statusPublished - 1 Jun 1994

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