Nanostructuring of ionic bridged silsesquioxanes

Amàlia Monge-Marcet; Xavier Cattoën; Philippe Dieudonné; Roser Pleixats; Michel Wong Chi Man

doi:10.1002/asia.201300538

Nanostructuring of ionic bridged silsesquioxanes

Amàlia Monge-Marcet, Xavier Cattoën, Philippe Dieudonné, Roser Pleixats, Michel Wong Chi Man

Department of Chemistry

Research output: Contribution to journal › Article › Research › peer-review

4 Citations (Scopus)

Abstract

The transformation by hydrolysis/condensation of four new mesityl-(bis or tris)imidazolium-based alkoxysilane precursors into their corresponding bridged silsesquioxanes has been investigated. These precursors feature urea groups and either short or long alkylene chains, which are known to favor self-assembly. The most regular nanostructures were obtained by a combination of the tripodal precursors with C10H20 alkylene chains, as shown by powder X-ray diffraction (PXRD) analysis, independent of the reaction conditions. Tidy up! Organosilicas that feature imidazolium units tend to self-organize during the sol-gel process thanks to the self-assembly of long alkylene chains. Copyright © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Original language	English
Pages (from-to)	2235-2241
Journal	Chemistry - An Asian Journal
Volume	8
Issue number	9
DOIs	https://doi.org/10.1002/asia.201300538
Publication status	Published - 1 Sept 2013

Keywords

hydrolysis
nanostructures
organosilicas
self-assembly
sol-gel processes

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title = "Nanostructuring of ionic bridged silsesquioxanes",

abstract = "The transformation by hydrolysis/condensation of four new mesityl-(bis or tris)imidazolium-based alkoxysilane precursors into their corresponding bridged silsesquioxanes has been investigated. These precursors feature urea groups and either short or long alkylene chains, which are known to favor self-assembly. The most regular nanostructures were obtained by a combination of the tripodal precursors with C10H20 alkylene chains, as shown by powder X-ray diffraction (PXRD) analysis, independent of the reaction conditions. Tidy up! Organosilicas that feature imidazolium units tend to self-organize during the sol-gel process thanks to the self-assembly of long alkylene chains. Copyright {\textcopyright} 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.",

keywords = "hydrolysis, nanostructures, organosilicas, self-assembly, sol-gel processes",

author = "Am{\`a}lia Monge-Marcet and Xavier Catto{\"e}n and Philippe Dieudonn{\'e} and Roser Pleixats and {Wong Chi Man}, Michel",

year = "2013",

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doi = "10.1002/asia.201300538",

language = "English",

volume = "8",

pages = "2235--2241",

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TY - JOUR

T1 - Nanostructuring of ionic bridged silsesquioxanes

AU - Monge-Marcet, Amàlia

AU - Cattoën, Xavier

AU - Dieudonné, Philippe

AU - Pleixats, Roser

AU - Wong Chi Man, Michel

PY - 2013/9/1

Y1 - 2013/9/1

N2 - The transformation by hydrolysis/condensation of four new mesityl-(bis or tris)imidazolium-based alkoxysilane precursors into their corresponding bridged silsesquioxanes has been investigated. These precursors feature urea groups and either short or long alkylene chains, which are known to favor self-assembly. The most regular nanostructures were obtained by a combination of the tripodal precursors with C10H20 alkylene chains, as shown by powder X-ray diffraction (PXRD) analysis, independent of the reaction conditions. Tidy up! Organosilicas that feature imidazolium units tend to self-organize during the sol-gel process thanks to the self-assembly of long alkylene chains. Copyright © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

AB - The transformation by hydrolysis/condensation of four new mesityl-(bis or tris)imidazolium-based alkoxysilane precursors into their corresponding bridged silsesquioxanes has been investigated. These precursors feature urea groups and either short or long alkylene chains, which are known to favor self-assembly. The most regular nanostructures were obtained by a combination of the tripodal precursors with C10H20 alkylene chains, as shown by powder X-ray diffraction (PXRD) analysis, independent of the reaction conditions. Tidy up! Organosilicas that feature imidazolium units tend to self-organize during the sol-gel process thanks to the self-assembly of long alkylene chains. Copyright © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

KW - hydrolysis

KW - nanostructures

KW - organosilicas

KW - self-assembly

KW - sol-gel processes

U2 - 10.1002/asia.201300538

DO - 10.1002/asia.201300538

M3 - Article

VL - 8

SP - 2235

EP - 2241

IS - 9

ER -

Nanostructuring of ionic bridged silsesquioxanes

Abstract

Keywords

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