NaAlH<inf>4</inf> confined in ordered mesoporous carbon

Christian Bonatto Minella; Inge Lindemann; Pau Nolis; Anja Kießling; Maria Dolors Baró; Markus Klose; Lars Giebeler; Bernd Rellinghaus; Jürgen Eckert; Ludwig Schultz; Oliver Gutfleisch

doi:https://doi.org/10.1016/j.ijhydene.2013.04.103

NaAlH<inf>4</inf> confined in ordered mesoporous carbon

Christian Bonatto Minella, Inge Lindemann, Pau Nolis, Anja Kießling, Maria Dolors Baró, Markus Klose, Lars Giebeler, Bernd Rellinghaus, Jürgen Eckert, Ludwig Schultz, Oliver Gutfleisch

Research output: Contribution to journal › Article › Research › peer-review

15 Citations (Scopus)

Abstract

In this paper we performed a comprehensive investigation of the structural and sorption properties of a 40 wt. % NaAlH4 confined in a ordered mesoporous carbon (OMC, i.e. CMK-3) by means of X-ray diffraction (XRD), transmission electron microscopy (TEM), 23Na{1H} and 27Al{1H} solid-state magic angle spinning-nuclear magnetic resonance (MAS-NMR). This study evidences a remarkable improvement of the sorption kinetics of NaAlH4 due to its existence in nanometer size within the OMC. The pressure composition isotherm (PCI) analysis (for the re-absorption step) of the nanoconfined NaAlH4 would suggest an alteration of its equilibrium thermodynamic properties. Copyright © 2013, Hydrogen Energy Publications, LLC. Published by Elsevier Ltd. All rights reserved.

Original language	English
Pages (from-to)	8829-8837
Journal	International Journal of Hydrogen Energy
Volume	38
DOIs	https://doi.org/10.1016/j.ijhydene.2013.04.103
Publication status	Published - 17 Jul 2013

Keywords

23 1 Na{ H} magic angle spinning-nuclear magnetic resonance
27 1 Al{ H} magic angle spinning-nuclear magnetic resonance
Complex hydride
Hydrogen storage
Nanoconfinement
Transmission electron microscopy

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https://doi.org/10.1016/j.ijhydene.2013.04.103

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title = "NaAlH4 confined in ordered mesoporous carbon",

abstract = "In this paper we performed a comprehensive investigation of the structural and sorption properties of a 40 wt. % NaAlH4 confined in a ordered mesoporous carbon (OMC, i.e. CMK-3) by means of X-ray diffraction (XRD), transmission electron microscopy (TEM), 23Na{1H} and 27Al{1H} solid-state magic angle spinning-nuclear magnetic resonance (MAS-NMR). This study evidences a remarkable improvement of the sorption kinetics of NaAlH4 due to its existence in nanometer size within the OMC. The pressure composition isotherm (PCI) analysis (for the re-absorption step) of the nanoconfined NaAlH4 would suggest an alteration of its equilibrium thermodynamic properties. Copyright {\textcopyright} 2013, Hydrogen Energy Publications, LLC. Published by Elsevier Ltd. All rights reserved.",

keywords = "23 1 Na{ H} magic angle spinning-nuclear magnetic resonance, 27 1 Al{ H} magic angle spinning-nuclear magnetic resonance, Complex hydride, Hydrogen storage, Nanoconfinement, Transmission electron microscopy",

author = "{Bonatto Minella}, Christian and Inge Lindemann and Pau Nolis and Anja Kie{\ss}ling and Bar{\'o}, {Maria Dolors} and Markus Klose and Lars Giebeler and Bernd Rellinghaus and J{\"u}rgen Eckert and Ludwig Schultz and Oliver Gutfleisch",

year = "2013",

month = jul,

day = "17",

doi = "https://doi.org/10.1016/j.ijhydene.2013.04.103",

language = "English",

volume = "38",

pages = "8829--8837",

journal = "International Journal of Hydrogen Energy",

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NaAlH<inf>4</inf> confined in ordered mesoporous carbon. / Bonatto Minella, Christian; Lindemann, Inge; Nolis, Pau; Kießling, Anja; Baró, Maria Dolors; Klose, Markus; Giebeler, Lars; Rellinghaus, Bernd; Eckert, Jürgen; Schultz, Ludwig; Gutfleisch, Oliver.

In: International Journal of Hydrogen Energy, Vol. 38, 17.07.2013, p. 8829-8837.

Research output: Contribution to journal › Article › Research › peer-review

TY - JOUR

T1 - NaAlH4 confined in ordered mesoporous carbon

AU - Bonatto Minella, Christian

AU - Lindemann, Inge

AU - Nolis, Pau

AU - Kießling, Anja

AU - Baró, Maria Dolors

AU - Klose, Markus

AU - Giebeler, Lars

AU - Rellinghaus, Bernd

AU - Eckert, Jürgen

AU - Schultz, Ludwig

AU - Gutfleisch, Oliver

PY - 2013/7/17

Y1 - 2013/7/17

N2 - In this paper we performed a comprehensive investigation of the structural and sorption properties of a 40 wt. % NaAlH4 confined in a ordered mesoporous carbon (OMC, i.e. CMK-3) by means of X-ray diffraction (XRD), transmission electron microscopy (TEM), 23Na{1H} and 27Al{1H} solid-state magic angle spinning-nuclear magnetic resonance (MAS-NMR). This study evidences a remarkable improvement of the sorption kinetics of NaAlH4 due to its existence in nanometer size within the OMC. The pressure composition isotherm (PCI) analysis (for the re-absorption step) of the nanoconfined NaAlH4 would suggest an alteration of its equilibrium thermodynamic properties. Copyright © 2013, Hydrogen Energy Publications, LLC. Published by Elsevier Ltd. All rights reserved.

AB - In this paper we performed a comprehensive investigation of the structural and sorption properties of a 40 wt. % NaAlH4 confined in a ordered mesoporous carbon (OMC, i.e. CMK-3) by means of X-ray diffraction (XRD), transmission electron microscopy (TEM), 23Na{1H} and 27Al{1H} solid-state magic angle spinning-nuclear magnetic resonance (MAS-NMR). This study evidences a remarkable improvement of the sorption kinetics of NaAlH4 due to its existence in nanometer size within the OMC. The pressure composition isotherm (PCI) analysis (for the re-absorption step) of the nanoconfined NaAlH4 would suggest an alteration of its equilibrium thermodynamic properties. Copyright © 2013, Hydrogen Energy Publications, LLC. Published by Elsevier Ltd. All rights reserved.

KW - 23 1 Na{ H} magic angle spinning-nuclear magnetic resonance

KW - 27 1 Al{ H} magic angle spinning-nuclear magnetic resonance

KW - Complex hydride

KW - Hydrogen storage

KW - Nanoconfinement

KW - Transmission electron microscopy

U2 - https://doi.org/10.1016/j.ijhydene.2013.04.103

DO - https://doi.org/10.1016/j.ijhydene.2013.04.103

M3 - Article

VL - 38

SP - 8829

EP - 8837

JO - International Journal of Hydrogen Energy

JF - International Journal of Hydrogen Energy

SN - 0360-3199

ER -

NaAlH<inf>4</inf> confined in ordered mesoporous carbon

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Keywords

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