TY - JOUR
T1 - Multifunctional MgFe2O4/GNPs nanocomposite :
T2 - graphene-promoted visible light driven photocatalytic activity and electrochemical performance of MgFe2O4 nanoparticles
AU - Israr, Muhammad
AU - Iqbal, Javed
AU - Arshad, Aqsa
AU - Gómez-Romero, Pedro
AU - Benages Vilau, Raúl
PY - 2020
Y1 - 2020
N2 - Herein, the electrochemical and photodegradation properties of magnesium ferrite and graphene-nanoplatelets nanocomposites, (MFO)(GNPs), (x = 0.25, 0.50, 0.75) are reported. Benefitting from the effective interfacial interaction of the bi-phase nanocomposite and superior electrical conduction of GNPs, a significant enhancement in supercapacitive performance has been demonstrated. Interestingly, the electrochemical properties of nanocomposite electrode were found to depend on the loading ratio of GNPs. Notably the (MFO)(GNPs) (50 wt % GNPs) shows an outstanding energy storage capacity i.e., 612 Fg¯¹ at 0.5 Ag¯¹ with 21.25 Wh kg¯¹ energy density at power density of 125 W kg¯¹ and retains ~76.8 % of the first cycle capacitance after continuous 1500 charge/discharge cycles. Furthermore, the (MFO)(GNPs) (25 wt % GNPs) composite demonstrates admirable photodegradation efficiency (99.3 % in 60 min of visible light illumination) which is 3.2 times than that of neat MFO nanoparticles. The superior electrochemical and photodegradation performance suggests that the prepared nanocomposites can be effectively utilized in high-performance energy storage devices and low cost, eco-friendly water purification systems.
AB - Herein, the electrochemical and photodegradation properties of magnesium ferrite and graphene-nanoplatelets nanocomposites, (MFO)(GNPs), (x = 0.25, 0.50, 0.75) are reported. Benefitting from the effective interfacial interaction of the bi-phase nanocomposite and superior electrical conduction of GNPs, a significant enhancement in supercapacitive performance has been demonstrated. Interestingly, the electrochemical properties of nanocomposite electrode were found to depend on the loading ratio of GNPs. Notably the (MFO)(GNPs) (50 wt % GNPs) shows an outstanding energy storage capacity i.e., 612 Fg¯¹ at 0.5 Ag¯¹ with 21.25 Wh kg¯¹ energy density at power density of 125 W kg¯¹ and retains ~76.8 % of the first cycle capacitance after continuous 1500 charge/discharge cycles. Furthermore, the (MFO)(GNPs) (25 wt % GNPs) composite demonstrates admirable photodegradation efficiency (99.3 % in 60 min of visible light illumination) which is 3.2 times than that of neat MFO nanoparticles. The superior electrochemical and photodegradation performance suggests that the prepared nanocomposites can be effectively utilized in high-performance energy storage devices and low cost, eco-friendly water purification systems.
KW - Graphene nanoplatelets
KW - Electrochemical capacitors
KW - Nanocomposites
KW - Electrode material
U2 - 10.1016/j.solidstatesciences.2020.106363
DO - 10.1016/j.solidstatesciences.2020.106363
M3 - Article
SN - 1293-2558
VL - 110
JO - Solid State Sciences
JF - Solid State Sciences
ER -