Multicomponent, Functionalized HKUST-1 Analogues Assembled via Reticulation of Prefabricated Metal-Organic Polyhedral Cavities

Jordi Faraudo, Arnau Carné-Sánchez, Daniel Maspoch Comamala, Akim Khobotov Bakishev, Cornelia von Baeckmann, Borja Ortín-Rubio, Laura Hernández-López, Alba Cortés-Martínez, Jordi Martínez-Esaín, Felipe Gándara, Judith Juanhuix, Ana Eva Platero-Prats

Research output: Contribution to journalArticleResearchpeer-review

6 Citations (Scopus)

Abstract

Metal-organic frameworks (MOFs) assembled from multiple building blocks exhibit greater chemical complexity and superior functionality in practical applications. Herein, we report a new approach based on using prefabricated cavities to design isoreticular multicomponent MOFs from a known parent MOF. We demonstrate this concept with the formation of multicomponent HKUST-1 analogues, using a prefabricated cavity that comprises a cuboctahedral Rh(II) metal-organic polyhedron functionalized with 24 carboxylic acid groups. The cavities are reticulated in three dimensions via Cu(II)-paddlewheel clusters and (functionalized) 1,3,5-benzenetricarboxylate linkers to form three- and four-component HKUST-1 analogues.
Original languageEnglish
Pages (from-to)15745-15753
Number of pages9
JournalJournal of the American Chemical Society
Volume144
Issue number34
DOIs
Publication statusPublished - 2022

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