Mineralization-Inspired Synthesis of Magnetic Zeolitic Imidazole Framework Composites

Anastasia Terzopoulou, Marcus Hoop, Xiang Zhong Chen, Ann M. Hirt, Michalis Charilaou, Yang Shen, Fajer Mushtaq, Angel Pérez del Pino, Constantin Logofatu, Laura Simonelli, Andrew J. de Mello, Christian J. Doonan, Jordi Sort, Bradley J. Nelson, Salvador Pané, Josep Puigmartí-Luis

Research output: Contribution to journalArticleResearch

16 Citations (Scopus)

Abstract

© 2019 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim Metal–organic frameworks (MOFs) capable of mobility and manipulation are attractive materials for potential applications in targeted drug delivery, catalysis, and small-scale machines. One way of rendering MOFs navigable is incorporating magnetically responsive nanostructures, which usually involve at least two preparation steps: the growth of the magnetic nanomaterial and its incorporation during the synthesis of the MOF crystals. Now, by using optimal combinations of salts and ligands, zeolitic imidazolate framework composite structures with ferrimagnetic behavior can be readily obtained via a one-step synthetic procedure, that is, without the incorporation of extrinsic magnetic components. The ferrimagnetism of the composite originates from binary oxides of iron and transition metals such as cobalt. This approach exhibits similarities to the natural mineralization of iron oxide species, as is observed in ores and in biomineralization.
Original languageEnglish
Pages (from-to)13550-13555
JournalAngewandte Chemie - International Edition
Volume58
DOIs
Publication statusPublished - 16 Sep 2019

Keywords

  • biomedical applications
  • magnetism
  • metal–organic frameworks
  • zeolitic imidazolate frameworks

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