Michael additions catalyzed by phosphines. An overlooked synthetic method

Carolina Gimbert; Maria Lumbierres; Caroline Marchi; Marcial Moreno-Mañas; Rosa M. Sebastián; Adelina Vallribera

doi:10.1016/j.tet.2005.07.005

Michael additions catalyzed by phosphines. An overlooked synthetic method

Carolina Gimbert, Maria Lumbierres, Caroline Marchi, Marcial Moreno-Mañas, Rosa M. Sebastián, Adelina Vallribera

Department of Chemistry

Research output: Contribution to journal › Article › Research › peer-review

77 Citations (Scopus)

Abstract

Triphenylphosphine and tributylphosphine are excellent catalysts for Michael additions. Many β-dicarbonyl compounds and electron-poor olefins, including sterically demanding partners, react successfully. The Michael addition catalyzed by phosphines deserves attention in its own right as a useful synthetic method. © 2005 Elsevier Ltd. All rights reserved.

Original language	English
Pages (from-to)	8598-8605
Journal	Tetrahedron
Volume	61
Issue number	36
DOIs	https://doi.org/10.1016/j.tet.2005.07.005
Publication status	Published - 5 Sep 2005

Keywords

β-Dicarbonyl compounds
Conjugate addition
Organocatalysis
Phosphines

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title = "Michael additions catalyzed by phosphines. An overlooked synthetic method",

abstract = "Triphenylphosphine and tributylphosphine are excellent catalysts for Michael additions. Many β-dicarbonyl compounds and electron-poor olefins, including sterically demanding partners, react successfully. The Michael addition catalyzed by phosphines deserves attention in its own right as a useful synthetic method. {\textcopyright} 2005 Elsevier Ltd. All rights reserved.",

keywords = "β-Dicarbonyl compounds, Conjugate addition, Organocatalysis, Phosphines",

author = "Carolina Gimbert and Maria Lumbierres and Caroline Marchi and Marcial Moreno-Ma{\~n}as and Sebasti{\'a}n, {Rosa M.} and Adelina Vallribera",

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T1 - Michael additions catalyzed by phosphines. An overlooked synthetic method

AU - Gimbert, Carolina

AU - Lumbierres, Maria

AU - Marchi, Caroline

AU - Moreno-Mañas, Marcial

AU - Sebastián, Rosa M.

AU - Vallribera, Adelina

PY - 2005/9/5

Y1 - 2005/9/5

N2 - Triphenylphosphine and tributylphosphine are excellent catalysts for Michael additions. Many β-dicarbonyl compounds and electron-poor olefins, including sterically demanding partners, react successfully. The Michael addition catalyzed by phosphines deserves attention in its own right as a useful synthetic method. © 2005 Elsevier Ltd. All rights reserved.

AB - Triphenylphosphine and tributylphosphine are excellent catalysts for Michael additions. Many β-dicarbonyl compounds and electron-poor olefins, including sterically demanding partners, react successfully. The Michael addition catalyzed by phosphines deserves attention in its own right as a useful synthetic method. © 2005 Elsevier Ltd. All rights reserved.

KW - β-Dicarbonyl compounds

KW - Conjugate addition

KW - Organocatalysis

KW - Phosphines

U2 - 10.1016/j.tet.2005.07.005

DO - 10.1016/j.tet.2005.07.005

M3 - Article

VL - 61

SP - 8598

EP - 8605

JO - Tetrahedron

JF - Tetrahedron

SN - 0040-4020

IS - 36

ER -