Metal complexes of 15-membered triolefinic macrocycles. (E,E,Z)-1,6,11-Tris[(2,4,6-triisopropylphenyl)sulfonyl]-1,6, 11-triazacyclopentadeca-3,8,13-triene and its palladium(0), platinum(0), and silver(I) complexes

Jordi Cortès; Marcial Moreno-Maas; Roser Pleixats

doi:10.1016/S0040-4039(01)00758-4

Metal complexes of 15-membered triolefinic macrocycles. (E,E,Z)-1,6,11-Tris[(2,4,6-triisopropylphenyl)sulfonyl]-1,6, 11-triazacyclopentadeca-3,8,13-triene and its palladium(0), platinum(0), and silver(I) complexes

Jordi Cortès, Marcial Moreno-Maas, Roser Pleixats

Department of Chemistry

Research output: Contribution to journal › Article › Research › peer-review

10 Citations (Scopus)

Abstract

The preparation of the 15-membered macrocycle (E,E,Z)-1,6,11-tris[(2,4,6-triisopropylphenyl)sulfonyl]-1,6, 11-triazacyclopentadeca-3,8,13-triene is reported. This cyclic triolefin forms stable complexes with palladium(0) and platinum(0), and a moderately stable complex with silver(I) tetrafluoroborate. © 2001 Elsevier Science Ltd.

Original language	English
Pages (from-to)	4337-4339
Journal	Tetrahedron Letters
Volume	42
Issue number	26
DOIs	https://doi.org/10.1016/S0040-4039(01)00758-4
Publication status	Published - 25 Jun 2001

Keywords

Macrocycles
Palladium
Platinum
Silver
Triene complexes

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10.1016/S0040-4039(01)00758-4

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title = "Metal complexes of 15-membered triolefinic macrocycles. (E,E,Z)-1,6,11-Tris[(2,4,6-triisopropylphenyl)sulfonyl]-1,6, 11-triazacyclopentadeca-3,8,13-triene and its palladium(0), platinum(0), and silver(I) complexes",

abstract = "The preparation of the 15-membered macrocycle (E,E,Z)-1,6,11-tris[(2,4,6-triisopropylphenyl)sulfonyl]-1,6, 11-triazacyclopentadeca-3,8,13-triene is reported. This cyclic triolefin forms stable complexes with palladium(0) and platinum(0), and a moderately stable complex with silver(I) tetrafluoroborate. {\textcopyright} 2001 Elsevier Science Ltd.",

keywords = "Macrocycles, Palladium, Platinum, Silver, Triene complexes",

author = "Jordi Cort{\`e}s and Marcial Moreno-Maas and Roser Pleixats",

year = "2001",

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doi = "10.1016/S0040-4039(01)00758-4",

language = "English",

volume = "42",

pages = "4337--4339",

journal = "Tetrahedron Letters",

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Metal complexes of 15-membered triolefinic macrocycles. (E,E,Z)-1,6,11-Tris[(2,4,6-triisopropylphenyl)sulfonyl]-1,6, 11-triazacyclopentadeca-3,8,13-triene and its palladium(0), platinum(0), and silver(I) complexes. / Cortès, Jordi; Moreno-Maas, Marcial; Pleixats, Roser.

In: Tetrahedron Letters, Vol. 42, No. 26, 25.06.2001, p. 4337-4339.

Research output: Contribution to journal › Article › Research › peer-review

TY - JOUR

T1 - Metal complexes of 15-membered triolefinic macrocycles. (E,E,Z)-1,6,11-Tris[(2,4,6-triisopropylphenyl)sulfonyl]-1,6, 11-triazacyclopentadeca-3,8,13-triene and its palladium(0), platinum(0), and silver(I) complexes

AU - Cortès, Jordi

AU - Moreno-Maas, Marcial

AU - Pleixats, Roser

PY - 2001/6/25

Y1 - 2001/6/25

N2 - The preparation of the 15-membered macrocycle (E,E,Z)-1,6,11-tris[(2,4,6-triisopropylphenyl)sulfonyl]-1,6, 11-triazacyclopentadeca-3,8,13-triene is reported. This cyclic triolefin forms stable complexes with palladium(0) and platinum(0), and a moderately stable complex with silver(I) tetrafluoroborate. © 2001 Elsevier Science Ltd.

AB - The preparation of the 15-membered macrocycle (E,E,Z)-1,6,11-tris[(2,4,6-triisopropylphenyl)sulfonyl]-1,6, 11-triazacyclopentadeca-3,8,13-triene is reported. This cyclic triolefin forms stable complexes with palladium(0) and platinum(0), and a moderately stable complex with silver(I) tetrafluoroborate. © 2001 Elsevier Science Ltd.

KW - Macrocycles

KW - Palladium

KW - Platinum

KW - Silver

KW - Triene complexes

U2 - 10.1016/S0040-4039(01)00758-4

DO - 10.1016/S0040-4039(01)00758-4

M3 - Article

VL - 42

SP - 4337

EP - 4339

JO - Tetrahedron Letters

JF - Tetrahedron Letters

SN - 0040-4039

IS - 26

ER -