Metal complexes of 15-membered triolefinic macrocycles. (E,E,Z)-1,6,11-Tris[(2,4,6-triisopropylphenyl)sulfonyl]-1,6, 11-triazacyclopentadeca-3,8,13-triene and its palladium(0), platinum(0), and silver(I) complexes

Jordi Cortès, Marcial Moreno-Maas, Roser Pleixats

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10 Citations (Scopus)

Abstract

The preparation of the 15-membered macrocycle (E,E,Z)-1,6,11-tris[(2,4,6-triisopropylphenyl)sulfonyl]-1,6, 11-triazacyclopentadeca-3,8,13-triene is reported. This cyclic triolefin forms stable complexes with palladium(0) and platinum(0), and a moderately stable complex with silver(I) tetrafluoroborate. © 2001 Elsevier Science Ltd.
Original languageEnglish
Pages (from-to)4337-4339
JournalTetrahedron Letters
Volume42
Issue number26
DOIs
Publication statusPublished - 25 Jun 2001

Keywords

  • Macrocycles
  • Palladium
  • Platinum
  • Silver
  • Triene complexes

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