Metal complexes in organic synthesis-V1 1 For Part IV, see Ref. 30. Alkylations of pentane-2,4-dione with allylic alcohols under palladium catalysis

M. Moreno-Mañas; A. Trius

doi:10.1016/S0040-4020(01)98915-X

Metal complexes in organic synthesis-V¹ 1 For Part IV, see Ref. 30. Alkylations of pentane-2,4-dione with allylic alcohols under palladium catalysis

M. Moreno-Mañas, A. Trius

Department of Chemistry

Research output: Contribution to journal › Article › Research › peer-review

25 Citations (Scopus)

Abstract

Pentane-2,4-dione with allylic alcohols or benzyl alcohol with palladium catalysts gives high yields of C-monoalkylated diketones, arising mainly from reaction at the terminal end of the allyic system for alkyl monosubstituted allyl alcohols. The effect of the catalyst on the alcohols has been evaluated; rearrangements and disproportionations have been observed. © 1981.

Original language	English
Pages (from-to)	3009-3015
Journal	Tetrahedron
Volume	37
Issue number	17
DOIs	https://doi.org/10.1016/S0040-4020(01)98915-X
Publication status	Published - 1 Jan 1981

Access to Document

10.1016/S0040-4020(01)98915-X

Cite this

@article{4eddb9a080b74f53aa5fa054f948d432,

title = "Metal complexes in organic synthesis-V1 1 For Part IV, see Ref. 30. Alkylations of pentane-2,4-dione with allylic alcohols under palladium catalysis",

abstract = "Pentane-2,4-dione with allylic alcohols or benzyl alcohol with palladium catalysts gives high yields of C-monoalkylated diketones, arising mainly from reaction at the terminal end of the allyic system for alkyl monosubstituted allyl alcohols. The effect of the catalyst on the alcohols has been evaluated; rearrangements and disproportionations have been observed. {\textcopyright} 1981.",

author = "M. Moreno-Ma{\~n}as and A. Trius",

year = "1981",

month = jan,

day = "1",

doi = "10.1016/S0040-4020(01)98915-X",

language = "English",

volume = "37",

pages = "3009--3015",

journal = "Tetrahedron",

issn = "0040-4020",

publisher = "Elsevier Limited",

number = "17",

}

TY - JOUR

T1 - Metal complexes in organic synthesis-V1 1 For Part IV, see Ref. 30. Alkylations of pentane-2,4-dione with allylic alcohols under palladium catalysis

AU - Moreno-Mañas, M.

AU - Trius, A.

PY - 1981/1/1

Y1 - 1981/1/1

N2 - Pentane-2,4-dione with allylic alcohols or benzyl alcohol with palladium catalysts gives high yields of C-monoalkylated diketones, arising mainly from reaction at the terminal end of the allyic system for alkyl monosubstituted allyl alcohols. The effect of the catalyst on the alcohols has been evaluated; rearrangements and disproportionations have been observed. © 1981.

AB - Pentane-2,4-dione with allylic alcohols or benzyl alcohol with palladium catalysts gives high yields of C-monoalkylated diketones, arising mainly from reaction at the terminal end of the allyic system for alkyl monosubstituted allyl alcohols. The effect of the catalyst on the alcohols has been evaluated; rearrangements and disproportionations have been observed. © 1981.

UR - https://www.scopus.com/pages/publications/0001375618

U2 - 10.1016/S0040-4020(01)98915-X

DO - 10.1016/S0040-4020(01)98915-X

M3 - Article

SN - 0040-4020

VL - 37

SP - 3009

EP - 3015

JO - Tetrahedron

JF - Tetrahedron

IS - 17

ER -

Metal complexes in organic synthesis-V¹ 1 For Part IV, see Ref. 30. Alkylations of pentane-2,4-dione with allylic alcohols under palladium catalysis

Abstract

Access to Document

Other files and links

Fingerprint

Cite this