Metal complexes in organic synthesis-V1 1 For Part IV, see Ref. 30. Alkylations of pentane-2,4-dione with allylic alcohols under palladium catalysis

M. Moreno-Mañas; A. Trius

doi:10.1016/S0040-4020(01)98915-X

Metal complexes in organic synthesis-V¹ 1 For Part IV, see Ref. 30. Alkylations of pentane-2,4-dione with allylic alcohols under palladium catalysis

M. Moreno-Mañas, A. Trius

Department of Chemistry

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Abstract

Pentane-2,4-dione with allylic alcohols or benzyl alcohol with palladium catalysts gives high yields of C-monoalkylated diketones, arising mainly from reaction at the terminal end of the allyic system for alkyl monosubstituted allyl alcohols. The effect of the catalyst on the alcohols has been evaluated; rearrangements and disproportionations have been observed. © 1981.

Original language	English
Pages (from-to)	3009-3015
Journal	Tetrahedron
Volume	37
Issue number	17
DOIs	https://doi.org/10.1016/S0040-4020(01)98915-X
Publication status	Published - 1 Jan 1981

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10.1016/S0040-4020(01)98915-X

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title = "Metal complexes in organic synthesis-V1 1 For Part IV, see Ref. 30. Alkylations of pentane-2,4-dione with allylic alcohols under palladium catalysis",

abstract = "Pentane-2,4-dione with allylic alcohols or benzyl alcohol with palladium catalysts gives high yields of C-monoalkylated diketones, arising mainly from reaction at the terminal end of the allyic system for alkyl monosubstituted allyl alcohols. The effect of the catalyst on the alcohols has been evaluated; rearrangements and disproportionations have been observed. {\textcopyright} 1981.",

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AU - Moreno-Mañas, M.

AU - Trius, A.

PY - 1981/1/1

Y1 - 1981/1/1

N2 - Pentane-2,4-dione with allylic alcohols or benzyl alcohol with palladium catalysts gives high yields of C-monoalkylated diketones, arising mainly from reaction at the terminal end of the allyic system for alkyl monosubstituted allyl alcohols. The effect of the catalyst on the alcohols has been evaluated; rearrangements and disproportionations have been observed. © 1981.

AB - Pentane-2,4-dione with allylic alcohols or benzyl alcohol with palladium catalysts gives high yields of C-monoalkylated diketones, arising mainly from reaction at the terminal end of the allyic system for alkyl monosubstituted allyl alcohols. The effect of the catalyst on the alcohols has been evaluated; rearrangements and disproportionations have been observed. © 1981.

U2 - 10.1016/S0040-4020(01)98915-X

DO - 10.1016/S0040-4020(01)98915-X

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IS - 17

ER -

Metal complexes in organic synthesis-V1 1 For Part IV, see Ref. 30. Alkylations of pentane-2,4-dione with allylic alcohols under palladium catalysis

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Metal complexes in organic synthesis-V¹ 1 For Part IV, see Ref. 30. Alkylations of pentane-2,4-dione with allylic alcohols under palladium catalysis