Metal complexes in organic synthesis-V1 1 For Part IV, see Ref. 30. Alkylations of pentane-2,4-dione with allylic alcohols under palladium catalysis

M. Moreno-Mañas, A. Trius

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Abstract

Pentane-2,4-dione with allylic alcohols or benzyl alcohol with palladium catalysts gives high yields of C-monoalkylated diketones, arising mainly from reaction at the terminal end of the allyic system for alkyl monosubstituted allyl alcohols. The effect of the catalyst on the alcohols has been evaluated; rearrangements and disproportionations have been observed. © 1981.
Original languageEnglish
Pages (from-to)3009-3015
JournalTetrahedron
Volume37
Issue number17
DOIs
Publication statusPublished - 1 Jan 1981

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