Magnetic properties of the low-temperature ferrimagnet [Cr(H2O)(NH3)5][FeCl6]

M. C. Morón; F. Palacio; J. Pons; J. Casabó

doi:10.1016/0304-8853(92)90261-L

Magnetic properties of the low-temperature ferrimagnet [Cr(H₂O)(NH₃)₅][FeCl₆]

M. C. Morón, F. Palacio, J. Pons, J. Casabó

Department of Chemistry

Research output: Contribution to journal › Article › Research › peer-review

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Abstract

We report on the magnetic properties of the complex bimetallic compound [Cr(H2O)(NH3)5][FeCl6] studied by ac magnetic susceptibility and magnetization techniques in the range 1.5-30 K and 0-40 kOe. The crystal structure contains discrete [Cr(H2O)(NH3)5]3+ and [FeCl6]3- ions, held together by ionic forces and by a network of hydrogen bonds. At temperatures below (2.32±0.01) K the compound seems to behave as a noncollinear ferrimagnet. In addition, the experimental H-T magnetic phase diagram has been derived. © 1992.

Original language	English
Pages (from-to)	243-245
Journal	Journal of Magnetism and Magnetic Materials
Volume	114
Issue number	3
DOIs	https://doi.org/10.1016/0304-8853(92)90261-L
Publication status	Published - 11 Aug 1992

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@article{3ce9449ccc49418fb358b5439181e7e3,

title = "Magnetic properties of the low-temperature ferrimagnet [Cr(H2O)(NH3)5][FeCl6]",

abstract = "We report on the magnetic properties of the complex bimetallic compound [Cr(H2O)(NH3)5][FeCl6] studied by ac magnetic susceptibility and magnetization techniques in the range 1.5-30 K and 0-40 kOe. The crystal structure contains discrete [Cr(H2O)(NH3)5]3+ and [FeCl6]3- ions, held together by ionic forces and by a network of hydrogen bonds. At temperatures below (2.32±0.01) K the compound seems to behave as a noncollinear ferrimagnet. In addition, the experimental H-T magnetic phase diagram has been derived. {\textcopyright} 1992.",

author = "Mor{\'o}n, {M. C.} and F. Palacio and J. Pons and J. Casab{\'o}",

year = "1992",

month = aug,

day = "11",

doi = "10.1016/0304-8853(92)90261-L",

language = "English",

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journal = "Journal of Magnetism and Magnetic Materials",

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TY - JOUR

T1 - Magnetic properties of the low-temperature ferrimagnet [Cr(H2O)(NH3)5][FeCl6]

AU - Morón, M. C.

AU - Palacio, F.

AU - Pons, J.

AU - Casabó, J.

PY - 1992/8/11

Y1 - 1992/8/11

N2 - We report on the magnetic properties of the complex bimetallic compound [Cr(H2O)(NH3)5][FeCl6] studied by ac magnetic susceptibility and magnetization techniques in the range 1.5-30 K and 0-40 kOe. The crystal structure contains discrete [Cr(H2O)(NH3)5]3+ and [FeCl6]3- ions, held together by ionic forces and by a network of hydrogen bonds. At temperatures below (2.32±0.01) K the compound seems to behave as a noncollinear ferrimagnet. In addition, the experimental H-T magnetic phase diagram has been derived. © 1992.

AB - We report on the magnetic properties of the complex bimetallic compound [Cr(H2O)(NH3)5][FeCl6] studied by ac magnetic susceptibility and magnetization techniques in the range 1.5-30 K and 0-40 kOe. The crystal structure contains discrete [Cr(H2O)(NH3)5]3+ and [FeCl6]3- ions, held together by ionic forces and by a network of hydrogen bonds. At temperatures below (2.32±0.01) K the compound seems to behave as a noncollinear ferrimagnet. In addition, the experimental H-T magnetic phase diagram has been derived. © 1992.

U2 - 10.1016/0304-8853(92)90261-L

DO - 10.1016/0304-8853(92)90261-L

M3 - Article

SN - 0304-8853

VL - 114

SP - 243

EP - 245

JO - Journal of Magnetism and Magnetic Materials

JF - Journal of Magnetism and Magnetic Materials

IS - 3

ER -

Magnetic properties of the low-temperature ferrimagnet [Cr(H2O)(NH3)5][FeCl6]

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Magnetic properties of the low-temperature ferrimagnet [Cr(H₂O)(NH₃)₅][FeCl₆]