Magnetic properties of the low-temperature ferrimagnet [Cr(H2O)(NH3)5][FeCl6]

M. C. Morón, F. Palacio, J. Pons, J. Casabó

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Abstract

We report on the magnetic properties of the complex bimetallic compound [Cr(H2O)(NH3)5][FeCl6] studied by ac magnetic susceptibility and magnetization techniques in the range 1.5-30 K and 0-40 kOe. The crystal structure contains discrete [Cr(H2O)(NH3)5]3+ and [FeCl6]3- ions, held together by ionic forces and by a network of hydrogen bonds. At temperatures below (2.32±0.01) K the compound seems to behave as a noncollinear ferrimagnet. In addition, the experimental H-T magnetic phase diagram has been derived. © 1992.
Original languageEnglish
Pages (from-to)243-245
JournalJournal of Magnetism and Magnetic Materials
Volume114
Issue number3
DOIs
Publication statusPublished - 11 Aug 1992

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