Macrocycles incorporating closo- and nido-carbaborane cages: molecular structure of 1,2-(3′-oxapentane-1′,5′-dithiolato-SS′)- 1′,2′-dicarba-closo-dodecaborane

Francesc Teixidor; Antonio M. Romerosa; Jordi Rius; Carles Miravitlles; Jaume Casabó; Clara Viñas; Eustaquio Sanchez

doi:10.1039/DT9900000525

Macrocycles incorporating closo- and nido-carbaborane cages: molecular structure of 1,2-(3′-oxapentane-1′,5′-dithiolato-SS′)- 1′,2′-dicarba-closo-dodecaborane

Francesc Teixidor, Antonio M. Romerosa, Jordi Rius, Carles Miravitlles, Jaume Casabó, Clara Viñas, Eustaquio Sanchez

Department of Chemistry

Research output: Contribution to journal › Article › Research › peer-review

52 Citations (Scopus)

Abstract

Reaction of 1,2-dimercapto-1,2-dicarba-closo-dodecaborane under basic conditions with appropriate dihalogenated organic compounds results in the formation of macrocycles incorporating 7,8-dicarbaundecaborate or 1,2-dicarba-closo-dodecaborane units. Polymers are obviated by using high dilution. The crystal structure of 1,2-(3′-oxapentane-1′,5′- dithiolato-SS′)-1′,2′-dicarba-closo-dodecaborane has been determined. It crystallizes in space group P21/a with four formula units in a cell of dimensions a = 11.708(2), b = 10.209(3), c = 12.613(3) Å, and β = 109.04(2)°.

Original language	English
Pages (from-to)	525-529
Journal	Journal of the Chemical Society, Dalton Transactions
Issue number	2
DOIs	https://doi.org/10.1039/DT9900000525
Publication status	Published - 1 Dec 1990

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Teixidor, F., Romerosa, A. M., Rius, J., Miravitlles, C., Casabó, J., Viñas, C., & Sanchez, E. (1990). Macrocycles incorporating closo- and nido-carbaborane cages: molecular structure of 1,2-(3′-oxapentane-1′,5′-dithiolato-SS′)- 1′,2′-dicarba-closo-dodecaborane. Journal of the Chemical Society, Dalton Transactions, (2), 525-529. https://doi.org/10.1039/DT9900000525

Teixidor, Francesc ; Romerosa, Antonio M. ; Rius, Jordi ; Miravitlles, Carles ; Casabó, Jaume ; Viñas, Clara ; Sanchez, Eustaquio. / Macrocycles incorporating closo- and nido-carbaborane cages: molecular structure of 1,2-(3′-oxapentane-1′,5′-dithiolato-SS′)- 1′,2′-dicarba-closo-dodecaborane. In: Journal of the Chemical Society, Dalton Transactions. 1990 ; No. 2. pp. 525-529.

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title = "Macrocycles incorporating closo- and nido-carbaborane cages: molecular structure of 1,2-(3′-oxapentane-1′,5′-dithiolato-SS′)- 1′,2′-dicarba-closo-dodecaborane",

abstract = "Reaction of 1,2-dimercapto-1,2-dicarba-closo-dodecaborane under basic conditions with appropriate dihalogenated organic compounds results in the formation of macrocycles incorporating 7,8-dicarbaundecaborate or 1,2-dicarba-closo-dodecaborane units. Polymers are obviated by using high dilution. The crystal structure of 1,2-(3′-oxapentane-1′,5′- dithiolato-SS′)-1′,2′-dicarba-closo-dodecaborane has been determined. It crystallizes in space group P21/a with four formula units in a cell of dimensions a = 11.708(2), b = 10.209(3), c = 12.613(3) {\AA}, and β = 109.04(2)°.",

author = "Francesc Teixidor and Romerosa, {Antonio M.} and Jordi Rius and Carles Miravitlles and Jaume Casab{\'o} and Clara Vi{\~n}as and Eustaquio Sanchez",

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Teixidor, F, Romerosa, AM, Rius, J, Miravitlles, C, Casabó, J, Viñas, C & Sanchez, E 1990, 'Macrocycles incorporating closo- and nido-carbaborane cages: molecular structure of 1,2-(3′-oxapentane-1′,5′-dithiolato-SS′)- 1′,2′-dicarba-closo-dodecaborane', Journal of the Chemical Society, Dalton Transactions, no. 2, pp. 525-529. https://doi.org/10.1039/DT9900000525

Macrocycles incorporating closo- and nido-carbaborane cages: molecular structure of 1,2-(3′-oxapentane-1′,5′-dithiolato-SS′)- 1′,2′-dicarba-closo-dodecaborane. / Teixidor, Francesc; Romerosa, Antonio M.; Rius, Jordi; Miravitlles, Carles; Casabó, Jaume; Viñas, Clara; Sanchez, Eustaquio.

In: Journal of the Chemical Society, Dalton Transactions, No. 2, 01.12.1990, p. 525-529.

Research output: Contribution to journal › Article › Research › peer-review

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T1 - Macrocycles incorporating closo- and nido-carbaborane cages: molecular structure of 1,2-(3′-oxapentane-1′,5′-dithiolato-SS′)- 1′,2′-dicarba-closo-dodecaborane

AU - Teixidor, Francesc

AU - Romerosa, Antonio M.

AU - Rius, Jordi

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AU - Sanchez, Eustaquio

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N2 - Reaction of 1,2-dimercapto-1,2-dicarba-closo-dodecaborane under basic conditions with appropriate dihalogenated organic compounds results in the formation of macrocycles incorporating 7,8-dicarbaundecaborate or 1,2-dicarba-closo-dodecaborane units. Polymers are obviated by using high dilution. The crystal structure of 1,2-(3′-oxapentane-1′,5′- dithiolato-SS′)-1′,2′-dicarba-closo-dodecaborane has been determined. It crystallizes in space group P21/a with four formula units in a cell of dimensions a = 11.708(2), b = 10.209(3), c = 12.613(3) Å, and β = 109.04(2)°.

AB - Reaction of 1,2-dimercapto-1,2-dicarba-closo-dodecaborane under basic conditions with appropriate dihalogenated organic compounds results in the formation of macrocycles incorporating 7,8-dicarbaundecaborate or 1,2-dicarba-closo-dodecaborane units. Polymers are obviated by using high dilution. The crystal structure of 1,2-(3′-oxapentane-1′,5′- dithiolato-SS′)-1′,2′-dicarba-closo-dodecaborane has been determined. It crystallizes in space group P21/a with four formula units in a cell of dimensions a = 11.708(2), b = 10.209(3), c = 12.613(3) Å, and β = 109.04(2)°.

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Macrocycles incorporating closo- and nido-carbaborane cages: molecular structure of 1,2-(3′-oxapentane-1′,5′-dithiolato-SS′)- 1′,2′-dicarba-closo-dodecaborane

Abstract

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